氧化锌纳米球的乙二醇辅助室温制备及其光学性质  

Ethylene glycol-assisted preparation and optical property of ZnO nanospheres at room temperature

作　　者：陈庆春[1] 

机构地区：[1]东华理工大学材料科学与工程系,江西抚州344000

出　　处：《无机盐工业》2015年第11期27-28,33,共3页Inorganic Chemicals Industry

基　　金：江西省教育厅科技项目(GJJ13449);东华理工大学省级重点建设学科(材料学)

摘　　要：以分析纯硫酸锌和氢氧化钠为主要原料。在液相体系中通过磁力搅拌的方法在室温下制备了氧化锌材料。其中。在体系中添加适量的乙二醇可以制备氧化锌纳米球。产物采用X射线衍射仪（XRD）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）、紫外可见吸收光度计（UV—vis）表征，结果表明：所得氧化锌材料不含杂质，氧化锌纳米球直径为30～70nm，吸收光谱具有明显的蓝移，推算其吸收带隙为3．33eV。ZnO materials were prepared by magnetic stirring at room temperature with ZnSO4 and NaOH at analytical grade as raw materials in a liquid system.ZnO nanospheres could be prepared with the aid of adding required amount of ethylene glycol into the system.The as-obtained products were characterized by powder X-ray diffraction （XRD）, scanning electron mi- croscope （（SEM）, transmission electron microscope （TEM）, and UV-vis spectroscopy （UV-vis）.Results showed that all products were pure ZnO without any impurity.And the diameter of the ZnO nanospheres was at 30-70 nm. The UV-vis spectrum of ZnO nanospheres was of obvious blue-shift compared with other products and the optical band gap of ZnO nanospheres was 3.33 eV after calculation.

关 键 词：氧化锌 纳米球 室温制备 光学性质 

分 类 号：TQ132.41[化学工程—无机化工]