金属卟啉配合物光解水制氢的性能研究  

Performance of Hydrogen Production from Water by Metal Porphyrin Complexes as Photolysis

作　　者：李光炎[1] 蔡秀兰[1] 杨原[1] 杨晓鑫[1] 张闯[1] 

机构地区：[1]广东药学院,广东广州510006

出　　处：《广东化工》2015年第21期25-26,共2页Guangdong Chemical Industry

摘　　要：金属卟啉配合物是一类广泛应用于光催化的材料。文章以对羟基苯甲醛、苯甲醛与吡咯为原料,合成了单羟基苯基卟啉化合物,并且与镍、铜、钴进行配位,得到3种金属配合物。在光照条件下,研究这些化合物分解水产氢的性能。Metal porphyrin complexes are widely used in photocatalytic materials. The monohydroxy porphyrin is synthesized by hydroxybenzaldehyde, benzaldehyde, and pyrrole, and with nickel, copper, cobalt is coordinated obtains three kinds of metal complexes. The capability of hydrogen production of these compounds is studied under the light conditions.

关 键 词：卟啉 配合物 光催化 

分 类 号：TQ116.2[化学工程—无机化工]