5-羟甲基糠醛转化为2,5-二甲基呋喃研究进展  

Research Progress on Catalytic Transformation of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran

作　　者：赵凯婉 肖文军[1] 彭家建[1] 徐大鹏[1] 厉嘉云[1] 白赢[1] 

机构地区：[1]杭州师范大学有机硅化学及材料技术教育部重点实验室,浙江杭州311121

出　　处：《广东化工》2015年第22期106-108,共3页Guangdong Chemical Industry

基　　金：国家自然科学基金(21303035)

摘　　要：2,5-二甲基呋喃(DMF)作为一种液体燃料,具有能量密度高、沸点高、辛烷值高、不溶于水以及污染小等优点,市场潜力巨大。DMF可由一种重要的平台化合物5-羟甲基糠醛(HMF)催化转化制得,在化石资源日益枯竭的今天,HMF催化转化为DMF反应过程研究非常重要,已越来越成为广受关注的焦点话题。文章对近年HMF转化为DMF的研究成果进行归纳总结,着重介绍所用金属催化剂的特点和催化机理,并对今后研究方向尤其是催化剂的设计方面进行展望。As a liquid fuel, 2,5-dimethylfuran （DMF） has a huge potential market for its high energy density, high boiling point, high octane number, undissolved in water, lower pollution, etc. DMF can be catalyzed from 5-hydroxymethylfurfural （HMF） that is considered as a very important platform compound. Nowadays, with the depletion of fossil resource, it is important to research on catalytic reaction process of transformation of DMF from HMF, and that become a locus of attention increasingly. In the review, the recent achievements of transformation of DMF from HMF are summarized, including characteristic of several metal catalysts and their catalytic mechanism. The future research trends especially about catalyst design are suggested.

关 键 词：5-羟甲基糠醛 2 5-二甲基呋喃 金属催化剂 

分 类 号：O643[理学—物理化学]