磺化杯芳烃的超分子组装体构筑及其功能  

Supramolecular Assemblies Based on p-Sulfonatocalixarenes and Their Functions

作　　者：王以轩[1] 刘育[1,2] 

机构地区：[1]南开大学化学系元素有机化学国家重点实验室,天津300071 [2]天津化学化工协同创新中心,天津300071

出　　处：《化学学报》2015年第10期984-991,共8页Acta Chimica Sinica

基　　金：973重大科学研究计划(No.2011CB932502);国家自然科学基金(Nos.91227107;21432004)资助~~

摘　　要：磺化杯芳烃具有非常强的分子键合能力,被广泛用于水相超分子自组装研究.介绍了磺化杯芳烃与客体阳离子形成超分子组装体的主要驱动力和形貌调控因素;总结了包括主体诱导客体聚集、客体诱导主体聚集及主客体共组装在内的三种主要聚集模式;并展望了其在刺激响应材料、药物传递载体、多功能超分子平台和超分子催化等领域的重要应用前景.Benefiting from the excellent host-guest binding capacity, p-sulfonatocalixarenes are widely used in the fabrication of versatile supramolecular assemblies in aqueous media. This review introduces the driving forces for supramolecular assembly based on the complexation ofp-sulfonatocalixarenes with cationic guests and the key factors for morphology control; three usual models for supramolecular assembly involving calixarene-induced guest assembly, guest-induced calixarene assembly and calixarene-guest coassembly; and the applications in stimuli-responsive materials, drug delivery, multifunctional nanoplatform, and supramolecular catalysis.

关 键 词：磺化杯芳烃 超分子组装 功能应用 

分 类 号：O641.3[理学—物理化学]