热化学铜-氯循环制氢进展  

Progress of hydrogen production by thermochemical Cu-Cl cycle

作　　者：何康昊[1] 宋江锋[1] 张志[1] 杨莞[1] 吕超[1] 赵萍[1] 

机构地区：[1]中国工程物理研究院,四川绵阳621900

出　　处：《现代化工》2015年第11期23-26,28,共5页Modern Chemical Industry

摘　　要：本文综述了四步铜-氯(Cu-Cl)热化学循环在质子交换膜电解、水解及电解-水解集成方面的研究进展,主要涉及高选择性质子交换膜及低极化、高活性电极催化剂制备;水解反应正、副反应机理探索;电解-水解集成工艺设计及相关装置研发。Recent progress of four-step thermochemical Cu-Cl cycle in proton exchange membrane （PEM） electrolysis, hydrolysis and electrolysis-hydrolysis integration is reviewed. The preparations of high selective PEMs and electrode catalysts with low polarization and high activity are highlighted. The mechanism of direct ＆ side hydrolysis reactions, process design of electrolysis-hydrolysis integration and development of related equipment are also introduced.

关 键 词：制氢 热化学循环 Cu-Cl循环 电解 水解 电解-水解集成 

分 类 号：TQ116.2[化学工程—无机化工] TK91[动力工程及工程热物理]