柠康酸酐的气相色谱分析  

Detection of citraconic anhydride with gas chromatography

作　　者：李博[1] 黄超明[1] 李毅[1] 肖英[1] 陈春玉[1] 谢辉辉[1] 

机构地区：[1]西南化工研究设计院有限公司,四川成都610225

出　　处：《现代化工》2015年第11期180-182,共3页Modern Chemical Industry

摘　　要：利用HP6890A气相色谱仪建立了一套测定柠康酸酐含量的方法,以SE-54毛细管柱(50 m×0.53 mm×1.00μm)为固定相,用氮气作为载气,使用氢火焰离子检测器,用马来酸酐作内标物,程序升温。气相回收率和重复性的测定结果表明,该方法准确度和精密度均较高,能够准确测定混合液中柠康酸酐的含量。The content of citraconic anhydride is analyzed by a gas chromatography in this study. Using HP6890A gas chromatography with hydrogen flame ionization detector,SE-54 capillary column （50m×0.53mm×1.00μm） as the stationary phase and cis-butenedioic anhydride as internal standard, a practical temperature programmed method for determination of citraeonic anhydride content is built up. The GC recovery and repeatability indicate that this method is accurate and precise for determination of content of citraconie anhydride in mixed liquid.

关 键 词：气相色谱 氢火焰检测器 内标法 柠康酸酐 马来酸酐 

分 类 号：O657.71[理学—分析化学]