Synthesis,Structure and Properties of a New Silver Nitrate Complex  

作　　者：崔毅鑫 杨文斌 谢兴昆 吴小园 卢灿忠 

机构地区：[1]College of Chemistry,Fuzhou University [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2015年第11期1697-1702,共6页结构化学（英文）

基　　金：supported by the Natural Science Foundation of Fujian Province(2012J06006,2006L2005)

摘　　要：A new metal-organic coordination polymer, [Ag（L）（NO3）]H （1, L = β-amino-β- （pyrid-2-yl）acrylonitrile）, has been synthesized by solvent method at ambient temperature and characterized through single-crystal diffraction, Fourier transformed infrared spectrum （FTIR）, elemental analysis, thermogravimetry analysis （TGA） and fluorescent measurements. 1 crystallizes in the triclinic system, space group Pi with a = 7.3600（3）, b = 8.5095（17）, c = 9.2936（14） A, α= 66.65（6）, β = 70.56（7）, γ= 71.59（6）°, V = 492.4（4） A3, μ = 2.043 mm-1, Dc = 2.104 Mg/m3, Z = 2, Mr = 312.01, F（000） = 302, the final R = 0.0347 and wR = 0.0987 for 3924 observed reflections with I 〉 2σ（I）.A new metal-organic coordination polymer, [Ag（L）（NO3）]H （1, L = β-amino-β- （pyrid-2-yl）acrylonitrile）, has been synthesized by solvent method at ambient temperature and characterized through single-crystal diffraction, Fourier transformed infrared spectrum （FTIR）, elemental analysis, thermogravimetry analysis （TGA） and fluorescent measurements. 1 crystallizes in the triclinic system, space group Pi with a = 7.3600（3）, b = 8.5095（17）, c = 9.2936（14） A, α= 66.65（6）, β = 70.56（7）, γ= 71.59（6）°, V = 492.4（4） A3, μ = 2.043 mm-1, Dc = 2.104 Mg/m3, Z = 2, Mr = 312.01, F（000） = 302, the final R = 0.0347 and wR = 0.0987 for 3924 observed reflections with I 〉 2σ（I）.

关 键 词：four-coordinate Ag（I） complex crystal structure PHOTOLUMINESCENCE 

分 类 号：O641.4[理学—物理化学]