Effect of Substituent Groups on the Syntheses of Two Ag Coordination Polymers Based on Tetrazole-yl Acylamide  

作　　者：陈二霞 刘娟 王飞 张健 

机构地区：[1]College of Materials Science and Engineering,Fuzhou University [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2015年第11期1729-1734,共6页结构化学（英文）

基　　金：Supported by NNSFC(91222105,21221001)

摘　　要：Two novel Ag coordination polymers based on tetrazole-yl acylamide, Ag（NTAA） （1, H-NTAA = N-（1H-tetrazol-5-yl）acetamide） and Ag（NTPA） （2, H-NTPA = N-（1H-tetrazol- 5-yl）propionamide） have been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction. Compound 1 features a 3-connected 4.82-fes network and compound 2 displays a ladder-like chain. The different structures between 1 and 2 are mainly related with the substituent groups oftetrazole-yl acylamide.Two novel Ag coordination polymers based on tetrazole-yl acylamide, Ag（NTAA） （1, H-NTAA = N-（1H-tetrazol-5-yl）acetamide） and Ag（NTPA） （2, H-NTPA = N-（1H-tetrazol- 5-yl）propionamide） have been synthesized under solvothermal conditions and characterized by single-crystal X-ray diffraction. Compound 1 features a 3-connected 4.82-fes network and compound 2 displays a ladder-like chain. The different structures between 1 and 2 are mainly related with the substituent groups oftetrazole-yl acylamide.

关 键 词：coordination polymers silver crystal structure TOPOLOGY electron donating 

分 类 号：O641.4[理学—物理化学]