全氟烷基丙烯酸酯共聚乳液的研究进展  

Research Progress in Perfluoroalkyl Acrylate Copolymer Emulsion

作　　者：罗源军[1] 吕太勇[1] 刘波[1] 张付宝[1] 李慧[1] 张建新[1] 

机构地区：[1]中昊晨光化工研究院有限公司,四川富顺643201

出　　处：《化工生产与技术》2015年第5期12-17,7,共6页Chemical Production and Technology

摘　　要：介绍了全氟烷基丙烯酸酯单体的合成、防水拒油的作用机理、共聚乳液的典型结构及其新的制备方法,简述了共聚乳液因具有良好的表面性能、耐候性及环境友好性而在纺织、皮革及涂料工业所获得的应用情况。认为如何降低全氟烷基丙烯酸酯共聚乳液的生产成本和提高它的综合性能,是今后设计合成这类产品的一个重要趋势;应加强与其他类型的整理剂之间协同效应与相容性的研究,拓宽全氟烷基丙烯酸酯共聚乳液应用领域。This paper reviewed the synthesis of perfluoroalkyl acrylate monomer, the action mechanism of water and oil repellent, the typical structure and the new preparation methods of the perfluoroalkyl acrylate copolymer emulsion. Due to superior properties the copolymer emulsion exhibit such as good surface properties, weatherability and environment friendly then had been used widely in the testile, leather and paint industry. The author raised the opinion that the important developing tendency of design and synthesis this kind products was how to reduce the production cost of perfluoroalkyl acrylate copolymer emulsion and improve its comprehensive performance. So we should strengthen the research on the synergistic effect between other types of finishing agent and compatibility,then broadened the application field of perfluoroalkyl acrylate copolymer emulsion.

关 键 词：全氟烷基丙烯酸酯 乳液聚合 作用机理 发展现状 

分 类 号：TQ316.334[化学工程—高聚物工业]