TANPyOPb(Ⅱ)含能配合物的合成,热分解行为及其对高氯酸铵热分解的催化作用（英文）  

An Energetic Pb(Ⅱ) Complex of TANPyO:Synthesis,Thermal Decomposition Behavior and Catalytic Effect on Thermal Decomposition of AP

作　　者：成健[1] 张荣仙 付代轩[3] 赵凤起[4] 徐司雨[4] 王晓鸣[5] 刘祖亮[1] 

机构地区：[1]南京理工大学化工学院,江苏南京210094 [2]江苏大学化学化工学院,江苏镇江212013 [3]四川石油射孔器材有限责任公司,四川内江642177 [4]西安近代化学研究所,陕西西安710065 [5]南京理工大学机械学院,江苏南京210094

出　　处：《含能材料》2015年第12期1162-1166,共5页Chinese Journal of Energetic Materials

基　　金：Five-Year(2011-2015) Pre-research Project(62201070102)

摘　　要：合成了2,4,6-三氨基-3,5-二硝基吡啶-1-氧化物(TANPyO)Pb(Ⅱ)含能配合物(Pb(TANPyO))。采用红外光谱、元素分析、撞击感度、摩擦感度、冲击波感度、TG-DTG和DSC表征了Pb(TANPyO)的结构和性能。采用TG-DTG和DSC分析了Pb(TANPyO)对高氯酸铵热分解的催化作用。结果表明:Pb(TANPyO)的分子式为Pb(C_5H_4N_6O_5)。配合物的撞击感度、摩擦感度和冲击波感度分别为305 cm,36 kg和4.9 mm。Pb(TANPyO)在50~600℃温度范围内只有一个分解放热峰,最大放热峰峰温为329.0℃,残渣量为23.8%。其放热分解反应的表观活化能为331.9 kJ·mol^(-1)。Pb(TANPyO)对AP的热分解具有显著的催化作用。An energetic Pb（Ⅱ） complex （Pb（TANPyO） ） of 2,4,6-triamino-3,5-dinitropyridine-1 -oxide （TANPyO） was synthesized. The structure and properties were characterized by FT-IR spectroscopy, elemental analysis, TG-DTG and DSC,and the impact sensitivity, friction sensitivity and shock wave sensitivity were studied as well. The catalytic effect of Pb（TANPyO） on the thermal decomposition of ammonium perchlorate （AP） was analyzed by TG-DTG and DSC. Results show that the molecular formula of Pb（TANPyO） is Pb（ Cs H4 N60s ）. The impact sensitivity, friction sensitivity and shock wave sensitivity are 305 cm, 36 kg and 4.9 mm, respectively. Pb（TANPyO） has an exothermic peak with summit peak at 329.0℃ in the temperature range of 50-500 ℃ with 23.8% residues. Its apparent activation energy of exothermic decomposition reaction is 331.9 kJ mol-1 . The Pb（TANPyO） has significant catalytic effect on the thermal decomposition of AP.

关 键 词：含能配合物 2 4 6-三氨基-3 5-二硝基吡啶-1-氧化物(TANPyO) 感度 热分解行为 催化作用 

分 类 号：TQ560.1[化学工程—炸药化工]