机构地区:[1]中国地质大学地球科学与资源学院,北京100083 [2]中国地质科学院地质研究所,北京100037 [3]昆明理工大学国土资源工程学院,昆明650093
出 处:《岩石学报》2015年第11期3363-3379,共17页Acta Petrologica Sinica
基 金:国家重点基础研究发展计划(973计划)(2015CB52601);国家自然科学基金项目(41273050;41373049;41320104004);中国地质调查局地质调查项目(12120114010301;1212011220908)联合资助
摘 要:兰坪盆地西缘发育一条重要的脉状Cu矿带,矿床的成矿流体来源一直存在较大的争议。本次研究对该矿带南段新发现的茅草坪矿床进行流体包裹体和H-O-C-S同位素研究,结合前人发表的该矿带矿床的同位素数据,探讨矿床成矿流体特征和来源。茅草坪矿床早(A1脉)、晚(A2脉)两期含矿石英脉中的流体包裹体均为含CO2盐水包裹体,可细分为含石盐子晶、富液相(水溶液相)、富气相(CO2相)包裹体等不同类型。根据流体包裹体的共生特点,将其划分为3组包裹体组合:(1)第I组,出现在A1脉石英中,为富液相(I-W型)、富气相(I-C型)和含石盐子晶(I-S型)包裹体共生;(2)第Ⅱ组,同样出现在A1脉石英中,为富液相(Ⅱ-W型)和富气相(Ⅱ-C型)包裹体共生;(3)第Ⅲ组,出现在A2脉石英中,为富液相(Ⅲ-W型)和富气相(Ⅲ-C型)包裹体共生。测温结果显示:I-S型包裹体均一温度在293~370℃之间,流体盐度为30.06%~39.76%Na Cleqv;Ⅱ-W型包裹体均一温度在302~490℃之间,流体盐度为1.23%~18.63%Na Cleqv;Ⅲ-W型包裹体均一温度在263~400℃之间,流体盐度为1.20%~11.34%Na Cleqv。同一组内,包裹体气/液相比高度变化,表明包裹体捕获时的流体呈不均一态,此时包裹体均一温度中低值部分近似代表该组包裹体真实的捕获温度。因此,从I组到Ⅲ组,包裹体分别捕获于280~320℃(I组、Ⅱ组)和260~280℃(Ⅲ组),结合盐度数据,反应初始成矿流体发生沸腾作用,伴随石盐子晶析出,流体盐度下降,随后温度降低。茅草坪矿床成矿流体富CO2的特点与区域内其他脉状Cu矿床一致,但盐度明显偏高。矿床热液石英的δDV-SMOW值变化在-94.6‰^-56.2‰之间,计算的流体的δ18OV-SMOW值集中在+8.1‰^+9.6‰之间,与区域其他脉状Cu矿床相似,数据主要落在原生岩浆水区域的下方,表明流体来源于岩浆水,但经历了开放系统下的脱气作用,没有盆地流体或大气降水的贡献;热液碳酸�An important vein Cu ore belt occurs in the western border of Lanping basin,western Yunnan,China. The origin of the ore-forming fluid of the deposit has been under great controversy. This paper investigates the fluid inclusions and H-O-C-S isotope in Maocaoping vein Cu deposit newly discovered in the southern section of the mine belt. Combining previous published isotopic data of the deposits in the mineralized belt,this paper discusses the features and source of the ore-forming fluid. Fluid inclusions in the orebearing quartz vein of the earlier( A1 vein) or the later( A2 vein) period are both CO2-bearing saline aqueous inclusions,which can be subdivided into halite-bearing inclusions,liquid-richen( aqueous phase) inclusions and vapor-richen( CO2phase) inclusions. In accordance with the symbiotic characteristics,fluid inclusions can be divided into three groups of assemblages.( 1) group I,appearing in A1 vein,which is enriched in liquid( type I-W),vapor( type I-C) and contains halite( type I-S);( 2) group Ⅱ,appearing in A1 vein as well,is a paragenetic association enriched in liquid( type Ⅱ-W) and vapor( type Ⅱ-C);( 3) group Ⅲ,appearing in A2 vein,is enriched inliquid( type Ⅲ-W) and vapor( typeⅢ-C). Micro-thermometric data of the fluid inclusions shows: Homogenization temperatures of type I-S range from 293 to 370℃ with salinity of 30. 06% ~ 39. 76% Na Cleqv; Homogenization temperatures of typeⅡ-W range from 302 to 490℃ with salinity of 1. 23% ~ 18. 63% Na Cleqv; Homogenization temperatures of type Ⅲ-W range from 263 to 400℃ with salinity of 1. 20% ~ 11. 34% Na Cleqv. Within the same group,the vapor / liquid ratio varies greatly,which implies an inhomogeneity of the trapping fluid. In this case,the lowest value of the homogenization temperature of the fluid inclusion represents the real temperature of trapping. Therefore,inclusions are captured in temperature ranging from 280 to 320℃( group I and Ⅱ) and from 260 to 280℃(
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