酞菁镍晶体的化学工艺合成与探究  

Process of Chemical Synthesis and Explore about Nickel Phthalocyanine Crystals

作　　者：夏道成[1] 任旭文 李万程[2] 

机构地区：[1]山西大同大学有机化学研究所,山西大同037009 [2]吉林大学物理学院集成光电子国家重点实验室,吉林长春130012

出　　处：《化学试剂》2015年第12期1140-1142,1145,共4页Chemical Reagents

基　　金：国家自然科学基金资助项目(61006034)

摘　　要：通过用1,3-二亚氨基异吲哚啉和二水乙酸合镍为反应原料,在不同有机溶剂中,以不同物质的量的催化剂,用溶剂热合成法直接合成酞菁镍晶体的过程,来探究酞菁镍晶体的最优化合成工艺。通过控制不同的反应条件,如反应温度、反应时间、催化剂等来确定反应最佳条件,为酞菁镍晶体的合成工艺提供理论依据。通过实验得出合成酞菁镍的最优化工艺条件是反应温度为270℃,溶剂为喹啉,体积为14 m L,反应时间为8 h。The solvothermal synthesis method of Ni Pc single crystals was studied by using 1,3-dimino-isoindoline and Ni（ Ac O）2·2H2O as starting materials in this article. The influences of the different temperatures,reaction time,solvent volumes and catalyst on the crystal yield were also discussed. Then the best reaction conditions which were temperature,time and catalyst were found.Thus,the synthetic method of nickel phthalocyanine crystals in industry was provided,and the highest Ni Pc crystal yield was under270 ℃ for 8 h in 14 m L quinoline.

关 键 词：酞菁镍 合成 反应条件 

分 类 号：O613.2[理学—无机化学]