秸秆塑料共热解水相产物分析及模物催化加氢研究  

Analysis of the Aqueous Phase Fraction from Co-pyrolysis of Straw/PP Mixture and Hydrodeoxygenation of Model Compound

作　　者：刘红波[1] 刘云凤 周政 吴强强 谭桂明 谢永荣[1] 卢新宁[1] 李剑[1] 华德润[1] 

机构地区：[1]赣南师范学院化学化工学院,江西赣州341000 [2]中原油田天然气分公司,河南濮阳457000

出　　处：《赣南师范学院学报》2015年第6期44-47,共4页Journal of Gannan Teachers' College(Social Science(2))

基　　金：国家自然科学基金项目(21176142)

摘　　要：用HPLC分析秸秆与塑料(PP)混合物热解产物水相的组成,水相有机组分主要由乙酸,呋喃和乙二醇等组成.根据分析结果,我们选择乙酸作为加氢脱氧的模型反应化合物.在高温条件下,加氢脱氧和脱羧反应同时进行.在高压低温条件下,加氢脱氧反应占优.最后,研究了加氢脱氧的机理.The component of the aqueous phase from co-pyrolysis of the mixture of straw/PP was analyzed by HPLC,which mainly consisted of acetic acid,furfural and glycol. According tothe result,acetic acidwasused ashydrodeoxygenation（ HDO） reactant. HDO and decarboxylation simultaneously occured at high temperature,and high pressure and low temperature favored HDO reaction. The mechanism of HDO was discussed.

关 键 词：生物质 共热解 催化剂 加氢脱氧 

分 类 号：TQ530[化学工程—煤化学工程]