油田注汽管道内盐沉积的特性  

Characteristics of Salt Deposition in Oilfield Steam Pipeline

作　　者：董滨[1] 翟小雨 许颖[1] 林森明 赵文学[3] 韩克江[3] 

机构地区：[1]同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室,上海200092 [2]新疆油田公司工程技术公司,新疆克拉玛依834000 [3]中国寰球工程公司,北京100012

出　　处：《石油化工》2015年第12期1524-1528,共5页Petrochemical Technology

基　　金：MPE-3重油高效集输关键技术研究项目(60058-00-0000-CA-002)

摘　　要：针对油田污水回用于热采锅炉导致注汽管道内壁盐沉积的问题,选取新疆油田某区注汽管道内积盐为试样,采用SEM,XRD,EDS,XPS等手段对积盐进行表征。探讨了注汽管道内积盐成因,并提出了防止和缓解积盐的措施。表征结果显示,注汽管道内壁附有的积盐呈规则块状,剖面平滑致密,外表面粗糙,可见大量针状物,主要组成为Na_2Si_2O_5和少量Na_2CO_3。实验结果表明,注汽锅炉给水中高浓度的NaCl不会沉积在管道内壁,积盐是进水中硅酸、碳酸氢钠、碳酸钠在高温、高压(12.6 MPa,486℃)条件下长时间作用形成的。增强蒸汽管道的保温措施,并控制回用污水中的硅含量可有效缓解注汽管道内盐沉积形成。When oilfield sewage was reused in thermal recovery boiler, salt deposition formed in steam pipeline in the Xinjiang oilfield. The salt deposition was characterized by means of SEM, XRD, EDS and XPS. The results showed that the salt deposition in steam pipeline was regular block shape with smooth dense section and rough surface, and its major components were Na2Si2O5 and a small amount ofNa2CO3, which formed due to the interaction of silicic acid, sodium bicarbonate and sodium carbonate in reused sewage under high temperature and high pressure（12.6 MPa and 486 ℃）, and high concentration sodium chloride in the reused sewage would not deposit in the pipeline. The formation of the salt deposition could be relieved through improving the heat preservation of the steam pipeline and controlling the silicon content in the reused sewage.

关 键 词：油田污水回用 热采锅炉 注汽管道 盐沉积 

分 类 号：X703[环境科学与工程—环境工程]