原子转移自由基聚合在分子结构设计中的应用进展  

The Research of ATRP Macromolecular Initiator and Application Process in the Molecular Structure Design

作　　者：牟思阳 郭静[1] 齐善威 杨利军[1] 宫玉梅[1] 张森[1] 

机构地区：[1]大连工业大学纺织与材料工程学院,大连116034

出　　处：《高分子通报》2015年第11期28-34,共7页Polymer Bulletin

基　　金：国家自然科学基金(51373027)

摘　　要：原子转移自由基聚合(ATRP)是一种新型"活性"/可控聚合技术,可有效地实现对聚合物分子结构的设计,精准地控制聚合物分子结构。本文在介绍了官能团反应法、偶联反应法以及自由基聚合法制备ATRP大分子引发剂的基础上,进一步介绍了通过控制大分子引发剂"活性"点位置进行聚合物结构设计。同时还着重综述了大分子引发剂在嵌段聚合物、梳状聚合物、分子刷聚合物、树状及超支化聚合物和星形聚合物分子设计中的应用。The Atom Transfer Radical Polymerization（ATRP） is a new type of controllable/active polymerization technology, which can effectively realize the structure design of the polymer molecular and precise control the polymer molecular structure. In this paper, we firstly introduce latest advances about the preparation methods of the ATRP macromolecular initiator in recent years, such as functional group reaction, coupling reaction and free radical polymerization. Then,we emphatically summarize the structure design of the the polymer through controlling the active position of macromolecules initiators briefly. Moreover, we focus on introducing the latest application of the macromolecular initiator through ATRP reaction in the structure design of the polymer, such as block polymers, comblike polymer, molecular brush polymer, dendritic polymers, branched polymer, star polymer.

关 键 词：ATRP 大分子引发剂 分子设计 进展 

分 类 号：TQ316.322[化学工程—高聚物工业]