Synthesis of （thia）Calixarene-based exTTF Derivatives and Their Electron Transfers Towards p-Chloranil and C60  

作　　者：ZHAO Bangtun CHEN Xiuhua MA Shuxiu ZHU Weimin 

机构地区：[1]College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, P R. China [2]College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China

出　　处：《Chemical Research in Chinese Universities》2015年第6期930-935,共6页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（Nos.21172105, 20872058）.

摘　　要：Two novel （thia）calixarene-based exTTF derivatives（3a and 3b） were prepared by Mitsunobu reactions in toluene using diethyl azodicarboxylate（DEAD） and triphenylphosphine（PPh3） system. The cyclic voltammograms of compounds 3a and 3b were provided, and two electron-irreversible waves with redox potentials were observed. Meanwhile, the intermolecular electron transfer（ET） properties of both compounds 3a and 3b towards p-chloranil（Q） and C60 were investigated via UV-Vis and fluorescent spectroscopies, respectively. The results indicated that the in- troduced nonoxidable metal ions（Al^3＋, Pb^2＋, Sc^3＋） might promote the intermolecular ET from compounds 3a and 3b towards Q ensembles, whereas the effects of Sc^3＋ were the most impressive. Furthermore, the effects of the same metal ions（Al^3＋, Pb^2＋, Sc^3＋） added for compound 3b were greater than those for compound 3a. Additionally, the pho- toinduced intermolecular ET from compounds 3a and 3b towards C60 was observed.Two novel （thia）calixarene-based exTTF derivatives（3a and 3b） were prepared by Mitsunobu reactions in toluene using diethyl azodicarboxylate（DEAD） and triphenylphosphine（PPh3） system. The cyclic voltammograms of compounds 3a and 3b were provided, and two electron-irreversible waves with redox potentials were observed. Meanwhile, the intermolecular electron transfer（ET） properties of both compounds 3a and 3b towards p-chloranil（Q） and C60 were investigated via UV-Vis and fluorescent spectroscopies, respectively. The results indicated that the in- troduced nonoxidable metal ions（Al^3＋, Pb^2＋, Sc^3＋） might promote the intermolecular ET from compounds 3a and 3b towards Q ensembles, whereas the effects of Sc^3＋ were the most impressive. Furthermore, the effects of the same metal ions（Al^3＋, Pb^2＋, Sc^3＋） added for compound 3b were greater than those for compound 3a. Additionally, the pho- toinduced intermolecular ET from compounds 3a and 3b towards C60 was observed.

关 键 词：exTTF CALIX[4]ARENE arene p-Chloranil（Q） C60 Electron transfer 

分 类 号：O644.1[理学—物理化学] O625.461[理学—化学]