Synthesis and Electrochemical Properties of a Novel Poly（ether sulfone） with Oligoaniline Pendants  

作　　者：LI Fangfei WANG Jiayu ZHOU Mingjuan LIU Xincai WANG Ce CHAO Danming 

机构地区：[1]State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, R R. China [2]College of Chemistry, Jilin University, Changchun 130012, P. R. China

出　　处：《Chemical Research in Chinese Universities》2015年第6期1066-1071,共6页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（No.21104024）, the Jilin Province Science and Technology Department Project, China（No.20130522139JH）, the Functional Research Funds for the Central Universities, China（No. JCKY-QKJC07） and the Open Project of State Key Laboratory of Superhard Materials（Jilin University）, China（No.201403）.

摘　　要：A novel poly（ether sulfone） with oligoaniline pendants（PESOP） was prepared by KaCO3-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry（FTIR）, 1H nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）. The cyclic voltammetry（CV） curve of PESOP reveals the reversible electroactivity. In the electrochromism study, PESOP film exhibited good electroch- romic properties with a high contrast value, moderate switching time and acceptable coloration efficiency. After running 1000 cycles, the PESOP/indium-tin oxide（ITO） electrochromic device remained unchanged except for the drifting of base line, which certified its good electro-photo stability of the fabricated electrochromic device. Moreover, the polarization technique and electrochemical impedance spectroscopy（EIS） were used to study the anticorrosion performance of PESOP coatings on the cold rolled steel（CRS） in a 5%（mass fraction） NaCI solution. All the results indicate that the obtained PESOP is a competitive candidate as anticorrosion material.A novel poly（ether sulfone） with oligoaniline pendants（PESOP） was prepared by KaCO3-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry（FTIR）, 1H nuclear magnetic resonance（1H NMR） and gel permeation chromatography（GPC）. The cyclic voltammetry（CV） curve of PESOP reveals the reversible electroactivity. In the electrochromism study, PESOP film exhibited good electroch- romic properties with a high contrast value, moderate switching time and acceptable coloration efficiency. After running 1000 cycles, the PESOP/indium-tin oxide（ITO） electrochromic device remained unchanged except for the drifting of base line, which certified its good electro-photo stability of the fabricated electrochromic device. Moreover, the polarization technique and electrochemical impedance spectroscopy（EIS） were used to study the anticorrosion performance of PESOP coatings on the cold rolled steel（CRS） in a 5%（mass fraction） NaCI solution. All the results indicate that the obtained PESOP is a competitive candidate as anticorrosion material.

关 键 词：ELECTROACTIVE OLIGOANILINE ELECTROCHROMISM ANTICORROSION 

分 类 号：O632.13[理学—高分子化学] TQ326.55[理学—化学]