A high-efficient amperometric hydrazine sensor based on novel electrospun CoFe_2O_4 spinel nanofibers  

作　　者：Juan Liu Jian Shen Mian Li Li-Ping Guo 

机构地区：[1]Faculty of Chemistry, Northeast Normal University [2]School of Chemical Engineering and Technology, Harbin Institute of Technology

出　　处：《Chinese Chemical Letters》2015年第12期1478-1484,共7页中国化学快报（英文版）

基　　金：the Fundamental Research Funds for the Central Universities(No.12SSXT145)

摘　　要：HeterojunctionFe2O3 nanoparticles（NPs）, NiFe2O4 nanofibers（NFs）, and CoFe2O4 NFs were synthesized by electrospinning and the subsequent thermal treatment processes. Characterization results indeed display the three-dimensional net-like textural structures of these as-electrospun spinel-type MFe2O4 NFs. The MFe2O4 NFs-based film configurations possess abundant micro/meso/macropores on their surface. These structures could afford more accessible transport channels for effective reduction of the mass transport resistance and improvement of the density of exposed catalytic active sites. All these advantages are responsible for the enhanced electro-catalytic performance of these MFe2O4 NFs in hydrazine oxidation. When used for hydrazine detection, CoFe2O4 NFs show the best catalytic efficiency.For example, the CoFe2O4 NFs possess a large sensitivity of 1327 mA cmà2（mmol Là1[à1in the linear range of 0.01 to 0.1 mmol Là1and 503 mA cmà2（mmol Là1）à1in the linear range of 0.1 to 11 mmol Là1, a response time of shorter than 3 s, good reproducibility and remarkable long-term stability. The superior catalytic efficiency, excellent stability, low cost, and ease of fabrication render CoFe2O4 NFs very promising materials in developing an electrochemical device that directly detects hydrazine.HeterojunctionFe2O3 nanoparticles（NPs）, NiFe2O4 nanofibers（NFs）, and CoFe2O4 NFs were synthesized by electrospinning and the subsequent thermal treatment processes. Characterization results indeed display the three-dimensional net-like textural structures of these as-electrospun spinel-type MFe2O4 NFs. The MFe2O4 NFs-based film configurations possess abundant micro/meso/macropores on their surface. These structures could afford more accessible transport channels for effective reduction of the mass transport resistance and improvement of the density of exposed catalytic active sites. All these advantages are responsible for the enhanced electro-catalytic performance of these MFe2O4 NFs in hydrazine oxidation. When used for hydrazine detection, CoFe2O4 NFs show the best catalytic efficiency.For example, the CoFe2O4 NFs possess a large sensitivity of 1327 mA cmà2（mmol Là1[à1in the linear range of 0.01 to 0.1 mmol Là1and 503 mA cmà2（mmol Là1）à1in the linear range of 0.1 to 11 mmol Là1, a response time of shorter than 3 s, good reproducibility and remarkable long-term stability. The superior catalytic efficiency, excellent stability, low cost, and ease of fabrication render CoFe2O4 NFs very promising materials in developing an electrochemical device that directly detects hydrazine.

关 键 词：hydrazine spinel fabrication subsequent render abundant afford diameters accessible shorter 

分 类 号：TQ340.64[化学工程—化纤工业] TP212[自动化与计算机技术—检测技术与自动化装置]