Lithium-ion transport in inorganic solid state electrolyte  

作　　者：高健 赵予生 施思齐 李泓 

机构地区：[1]Institute of Physics Chinese Academy of Sciences [2]Materials Genome Institute Shanghai University [3]Department of Physics and Astronomy and High Pressure Science and Engineering Center University of NevadaLas Vegas Nevada 89154 [4]School of Materials Science and Engineering Shanghai University

出　　处：《Chinese Physics B》2016年第1期139-173,共35页中国物理B（英文版）

基　　金：supported by the National Natural Science Foundation of China(Grant No.51372228);the Shanghai Pujiang Program,China(Grant No.14PJ1403900);the Shanghai Institute of Materials Genome from the Shanghai Municipal Science and Technology Commission,China(Grant No.14DZ2261200)

摘　　要：An overview of ion transport in lithium-ion inorganic solid state electrolytes is presented, aimed at exploring and de signing better electrolyte materials. Ionic conductivity is one of the most important indices of the performance of inorganic solid state electrolytes. The general definition of solid state electrolytes is presented in terms of their role in a working cell （to convey ions while isolate electrons）, and the history of solid electrolyte development is briefly summarized. Ways of using the available theoretical models and experimental methods to characterize lithium-ion transport in solid state elec- trolytes are systematically introduced. Then the various factors that affect ionic conductivity are itemized, including mainly structural disorder, composite materials and interface effects between a solid electrolyte and an electrode. Finally, strategies for future material systems, for synthesis and characterization methods, and for theory and calculation are proposed, aiming to help accelerate the design and development of new solid electrolytes.An overview of ion transport in lithium-ion inorganic solid state electrolytes is presented, aimed at exploring and de signing better electrolyte materials. Ionic conductivity is one of the most important indices of the performance of inorganic solid state electrolytes. The general definition of solid state electrolytes is presented in terms of their role in a working cell （to convey ions while isolate electrons）, and the history of solid electrolyte development is briefly summarized. Ways of using the available theoretical models and experimental methods to characterize lithium-ion transport in solid state elec- trolytes are systematically introduced. Then the various factors that affect ionic conductivity are itemized, including mainly structural disorder, composite materials and interface effects between a solid electrolyte and an electrode. Finally, strategies for future material systems, for synthesis and characterization methods, and for theory and calculation are proposed, aiming to help accelerate the design and development of new solid electrolytes.

关 键 词：lithium-ion batteries solid state electrolyte ionic conductivity ion transport mechanism 

分 类 号：TM912[电气工程—电力电子与电力传动]