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作 者:程伟东 顾晓华 宋雪 曾鹏 吴昭君 邢雪青 默广 吴忠华
机构地区:[1]College of Materials Science and Engineering,Qiqihar University,Qiqihar 161006,China [2]Department of Practice Teaching and Equipment Management,Qiqihar University,Qiqihar 161006,China [3]Institute of High Energy Physics,Chinese Academy of Sciences,Beijing lO0099,China
出 处:《Chinese Physics B》2016年第1期783-788,共6页中国物理B(英文版)
基 金:supported by the National Natural Science Foundation of China(Grant Nos.U1232203,U1432104,U1332107,11305198,and 11405199);the Program for Young Teachers Scientific Research in Qiqihar University,China(Grant No.2012k-Z02);the Natural Science Foundation of Heilongjiang Province,China(Grant No.E201259)
摘 要:The nanostructures during the tensile drawing of poly(ethylene terephthalate) (PET)/hexadecyl triphenyl phospho- nium bromide montmorillonite (PMMT) nanocomposites were studied by in-situ small angle x-ray scattering. For strain higher than the yield point, the scattering intensity increases dramatically due to the nucleation and growth of nanovoids and crystals. The nanovoids and crystals are significantly dependent on the heating temperature. The effective filling of PMMT in the PET matrix provokes a strong restriction to the long period. The peaks of the long period disappear gradually with the deformation strain increasing from 0% to 34%.The nanostructures during the tensile drawing of poly(ethylene terephthalate) (PET)/hexadecyl triphenyl phospho- nium bromide montmorillonite (PMMT) nanocomposites were studied by in-situ small angle x-ray scattering. For strain higher than the yield point, the scattering intensity increases dramatically due to the nucleation and growth of nanovoids and crystals. The nanovoids and crystals are significantly dependent on the heating temperature. The effective filling of PMMT in the PET matrix provokes a strong restriction to the long period. The peaks of the long period disappear gradually with the deformation strain increasing from 0% to 34%.
关 键 词:small angle x-ray scattering NANOSTRUCTURE MONTMORILLONITE poly(ethylene terephthalate)
分 类 号:TB33[一般工业技术—材料科学与工程]
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