离子液体/H_2SO_4催化烷氧基取代苯和萘的需氧碘化（英文）  

Ionic Liquid / H_2SO_4 Catalyzed Aerobic Iodination of Alkoxyl-Substituted Benzenes and Naphthalines

作　　者：任运来[1] 王胚 田欣哲[1] 李福伟[2] 王斌玉 王键吉[3] 

机构地区：[1]河南科技大学化工与制药学院,河南洛阳471023 [2]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000 [3]河南师范大学化学化工学院绿色化学介质与反应省部共建教育部重点实验室,河南新乡453007

出　　处：《分子催化》2015年第6期505-512,共8页Journal of Molecular Catalysis(China)

基　　金：sponsored by the Open Project of State Key Laboratory for Oxo Synthesis and Selective Oxidation(Grant No.OSSO-2015-21);the Program for Science&Technology Innovation Talents in Universities of Henan Province(Grant No.15HASTIT004)

摘　　要：使用离子液体[Bmim][NO3]作为溶剂和催化剂,进行分子氧的活化,实现了芳烃的需氧碘化,为碘代芳烃的合成提供了一种有应用潜力的方法.在40℃的温和条件下,一系列烷氧基取代苯和萘化合物能够顺利地进行需氧碘化,得到的产率和选择性大部分高于85%.由于碘源中的原子几乎都能够转移到最终产品中,因此这个方法具有较高的原子经济性.The ionic liquid 1-butyl-3-methylimidazolium nitrate（ [Bmim][NO3]） was introduced as both the solvent and catalyst for the activation of the molecular oxygen related to the aerobic iodination of arenes,which provides an effective and practical strategy for the synthesis of aryl iodides. The presented procedure allows a series of alkoxyl-substituted benzenes and naphthalines to undergo the aerobic iodination in high yields and excellent selectivities at an ambient temperature of 40 ℃.Almost all the atoms in the iodine source can be transferred to the final products.

关 键 词：碘化 离子液体 催化 芳烃 

分 类 号：O643.32[理学—物理化学]