溶剂热法制备二氧化硅包覆硫化铈红色色料的研究  

Preparation of SiO_2 coated γ-Ce_2S_3 Red Pigment by Solvent Hot Method

作　　者：章彧[1,2] 李月明[1,2] 谢志翔[1,2] 沈宗洋[1,2] 王竹梅[1,2] 

机构地区：[1]景德镇陶瓷学院材料科学与工程学院,景德镇333403 [2]江西省先进陶瓷材料重点实验室,景德镇333403

出　　处：《中国陶瓷》2015年第12期68-72,共5页China Ceramics

基　　金：国家自然科学基金(51462010)

摘　　要：采用正硅酸乙酯(TEOS)为硅原、聚乙烯吡咯烷酮(PVP)为分散剂、去离子水和乙醇为反应介质,以氨水为pH调节剂,在120℃水热釜中对市售硫化铈(γ-Ce_2S_3)红色料进行包裹。研究了正硅酸乙酯(TEOS)添加量对γ-Ce_2S_3包覆效果的影响。结果表明:当Ce:Si的摩尔比为1:3时,在γ-Ce_2S_3颗粒表面形成SiO_2包覆层的效果最佳,且该SiO_2包覆γ-Ce_2S_3色料在空气条件下的分解温度相比未包覆的γ-Ce_2S_3色料有显著提高,从350℃提高至550℃左右。Commercially available gammacerium sulfide（γ-Ce_2S_3） was coated using ethyl silicate（TEOS） as silicon source,polyvinyl pyrrolidone（PVP） as dispersant,deionized water and alcohol as reaction medium and ammonia as pH conditioning agent in a hydrothermal reaction kettle at 120 °C.The influence of ethyl silicate content on the coating effect of γ-Ce_2S_3 was investigated.The results showed that the grain surface of γ-Ce_2S_3 can be well covered by SiO_2layer when the mole ratio of Ce：Si was 1：3,and the decomposition temperature of SiO_2-coated γ-Ce_2S_3 under the air condition was strongly elevated as compared to that of uncoated γ-Ce_2S_3,from 350 °C to 550 °C.

关 键 词：γ-Ce2S3 SIO2 红色色料 硅铈比 分解温度 

分 类 号：TQ174.4[化学工程—陶瓷工业]