PhI(OAc)_2/I_2介导下氮烷氧基酰胺的氧化自身偶联成酯的方法  

PhI(OAc)_2/I_2-Mediated Oxidative Homocoupling of N-Alkoxyamides:An Approach to Esters

作　　者：段希焱[1] 段希斌[2] 杨坤[1] 王志成[1] 张璐[1] 佟悦[1] 刘浩哲[1] 杜珂[1] 唐榕泽 

机构地区：[1]河南科技大学化工与制药学院,洛阳471023 [2]郑州大学附属郑州中心医院,郑州450007

出　　处：《有机化学》2015年第12期2552-2558,共7页Chinese Journal of Organic Chemistry

基　　金：河南科技大学博士科研启动项目(No.4008-13480042)~~

摘　　要：一系列取代的氮烷氧基酰胺衍生物能够在PhI(OAc)_2/I_2催化下转化成相应的酯.这个新颖的合成策略能够有效地合成酯类化合物.该反应具有原料易得,反应温和,底物范围广,非过渡金属催化等特点.A variety of substituted N-alkoxyamides derivatives were found to be converted to the corresponding esters mediated by PhI（OAC）2/I2. This novel strategy allows for an efficient synthesis of esters and is highlighted by appealing features such as readily available of the starting material, mild reaction condition, wide substrate scope and transition-metal-free characteristics.

关 键 词：高价碘 氮烷氧基酰胺 酯 氧化偶联 

分 类 号：O623.624[理学—有机化学]