H_2O_2氧化环己烯合成己二酸的催化剂研究进展  

Advances in research of catalyst for synthesis of adipic acid through oxidation of cyclohexene with H_2O_2

作　　者：包德才[1] 白丽珍[1] 赵岩[1] 任冬梅[1] 夏云生[1] 赵莹莹[1] 李新华[1] 

机构地区：[1]渤海大学化学化工学院,辽宁锦州121013

出　　处：《渤海大学学报（自然科学版）》2015年第4期319-326,共8页Journal of Bohai University:Natural Science Edition

基　　金：国家自然科学基金项目(No:21076026);渤海大学博士启动基金(No:BSQD201416);渤海大学博士启动基金(No:BSQD201417);辽宁省教育厅基金项目(No:L2013430)

摘　　要：己二酸是工业上具有重要应用的二元羧酸,近年来其绿色合成工艺受到广泛关注.其中H_2O_2氧化环己烯合成途径因其操作简单,反应条件温和,具有良好的发展前景.以该体系为基础,对反应过程中催化剂的研究成果从钨系、钛系和其它体系三个方面进行详细总结,并分析了多相催化剂研究的发展趋势.Adipic acid is a binary carboxylic acid has the important industry application, and its green syn- thesis process has been widely attention in recent years, Among which, the synthesis process of oxidising cyclo- hexene with H2 O2 has good prospects for its simple operation and mild reaction conditions. On the basis of the system above, a detailed overview of the research results was described from three aspects of tungsten, titanium and other catalyst system the used in the process and the research trend of the development of heterogeneous sys- tem was analyzed.

关 键 词：环己烯 己二酸 H2O2 钨 钛 绿色合成 

分 类 号：O643.3[理学—物理化学]