芳香族-长碳链脂肪族PA611-co-I的合成及表征  

Synthesis and characterization of aromatic-long carbon chain aliphatic polyamide 611-co-imide

作　　者：史越[1] 曹梦[1] 罗钟琳[1] 王标兵[1] 

机构地区：[1]常州大学材料科学与工程学院,常州213164

出　　处：《化工新型材料》2016年第1期101-103,共3页New Chemical Materials

摘　　要：采用Yamazaki膦酰化反应的方法,以预制的酰亚胺二酸单体和1,6-己二胺为原料,亚磷酸三苯酯和吡啶为缩合剂合成一种新型聚酰胺-酰亚胺(PAI)PA611-co-I,其中酰亚胺二酸单体是以1,2,4,5-均苯四甲酸二酐和11-氨基十一烷酸在冰醋酸中合成。通过FT-IR、1 H-NMR、13 C-NMR、WAXD、DSC、TGA等表征了所制备的酰亚胺二酸单体和聚合物的结构及性能。结果表明,PAI是一种半结晶性聚合物,具有优异的的热稳定性以及很高的玻璃化温度和熔点。PA611-co-I（PAI）was prepared via Yamazaki phosphorylation polycondensation from imide ring-preformed diimide-dicarboxylic acid（DIDA）with 1,6-hexylenediamime using triphenyl phosphite and pyridine as condensing agents.The structures of DIDA and PA611-co-I were confirmed using fourier transform infrared spectroscopy（FT-IR）,nuclear magnetic resonance spectroscopy（NMR）and wide-angle X-ray diffraction（WAXD）.The thermal property of PA611-co-I was investigated by differential scanning calorimeter（DSC）and thermogravimetric analysis（TGA）.The results showed that the PA611-co-I was semicrystalline,and exhibited high glass transition temperature and melting temperature as well as good thermal stability.

关 键 词：Yamazaki膦酰化反应 芳香族-脂肪族聚酰胺-酰亚胺 半结晶 热稳定性 

分 类 号：O633.22[理学—高分子化学]