溶胶-凝胶法制备xLiFePO_4·yLi_3V_2(PO_4)_3/C复合正极材料及其电化学性能研究（英文）  

Preparation and Electrochemical Properties of Nano-sized xLiFePO_4·yLi_3V_2(PO_4)_3/C Composite Cathode Materials via a Sol-gel Method

作　　者：晏兵[1] 高朋召[1] 李冬云[2] 田光磊[2] 刘伟[3] 孙玉坤 

机构地区：[1]湖南大学,湖南长沙410082 [2]中国计量学院,浙江杭州310018 [3]清华大学新型陶瓷与精细工艺国家重点实验室,北京100084

出　　处：《稀有金属材料与工程》2016年第S1期24-27,共4页Rare Metal Materials and Engineering

基　　金：Hunan University“Young Teachers Program”(2014);Natural Sciences Fund of Zhejiang Province,China(LY14E020009)

摘　　要：采用溶胶-凝胶法制备出电化学性能优异的xLiFePO4·yLi3V2（PO4）3/C复合正极材料。研究了复合比例对材料的组成、微观结构和电化学性能的影响。结果表明,当LiFePO4和Li3V2（PO4）3的摩尔比为7:1,所得复合材料的颗粒尺寸在4080nm之间,颗粒表面均匀地覆盖了一层无定形碳。在0.1C倍率下的首次放电容量为129.7mAh/g,充放电效率为96.0%;在1C、2C和5C倍率下,该材料的首次放电容量分别为104.6,89.3,71.6mAh/g,30次循环后的容量保持率为99.9%、95.1%和98.6%,表现出了良好的电化学稳定性。The xLiFePO_4·y Li_3V_2(PO_4)_3/C composite cathode materials were prepared via a sol-gel method. Influence of the proportion on the composition, microstructure and electrochemical performance of the composites were studied. Results show that the obtained composites are composed of Li Fe PO4 with olivine structure, Li_3V_2(PO_4)_3 with monoclinic structure and slight Li_(0.6)V_(1.67)O_(3.67) impurity phases. The particles of the composites are uniformly coated with an amorphous carbon layer and exhibit fine crystal sizes between 40 and 80 nm. When molar ratio of LiFePO_4 and Li_3V_2(PO_4)_3 is 7:1, the first discharge capacity of the composites reaches 129.7 m Ah/g with a charge and discharge efficiency of 96.0% at 0.1 C rate. At 1 C, 2 C and 5 C rate, the first discharge capacities are 104.6, 89.3 and 71.6 m Ah/g, respectively. After 30 cycles, the capacity retentions are 99.9%, 95.1%, 98.6%, respectively, showing a good electrochemical stability.

关 键 词：复合正极材料 xLiFePO4·yLi3V2(PO4)3/C 显微结构 电化学性能 

分 类 号：TM912[电气工程—电力电子与电力传动] TB332[一般工业技术—材料科学与工程]