Fabrication and Characterization of Gecko-inspired Dry Adhesion, Superhydrophobicity and Wet Self-cleaning Surfaces  

作　　者：Yongchao Zhang Shuxin Qu Xiang Cheng Xueling Gao Xia Guo 

机构地区：[1]Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China [2]The Hong Kong Polytechnic University, Department of Rehabilitation Sciences, Kowloon, Hong Kong 999077, China

出　　处：《Journal of Bionic Engineering》2016年第1期132-142,共11页仿生工程学报（英文版）

摘　　要：In this study, gecko-inspired polydimethylsiloxane （PDMS） microfiber surfaces were fabricated by combining Inductively Coupled Plasma （ICP） and micro-mold casting. The effect of roughness and surface energy of counterface on the adhesion of gecko-inspired microflber surfaces and its superhydrophobicity and wet self-cleaning were studied. The adhesion of gecko-inspired microfiber surfaces depended on the roughness of the eounterfaces due to the influences of contact area and interlocking mechanism. SEM images of interfaces between counterfaces with different roughness and gecko-inspired mi- crofiber surfaces revealed the matched and dis-matched contact directly. The gecko-inspired microfiber surface got the larger adhesive force from the higher surface energy counterface, which is consisted with Johnson-Kendall-Roberts （JKR） theory. The smaller dimension and lower duty ratio of microfibers on PDMS resulted in the increasing of Water Contact Angle （WCA） and the decreasing of Sliding Angle （SA） compared to those of smooth PDMS. Particularly, sample P-8-28-20 had the biggest WCA （155°） and SA （7°）, which displayed the superhydrophobicity and the best wet self-cleaning efficiency in all samples. The present studies showed that the roughness and surface energy of counterface both affected the adhesion of gecko-inspired microfiber surfaces. The smaller dimension and lower duty ratio of microfibers on PDMS endowed it with the superhydro- phobicity and the wet self-cleaning abilities.In this study, gecko-inspired polydimethylsiloxane （PDMS） microfiber surfaces were fabricated by combining Inductively Coupled Plasma （ICP） and micro-mold casting. The effect of roughness and surface energy of counterface on the adhesion of gecko-inspired microflber surfaces and its superhydrophobicity and wet self-cleaning were studied. The adhesion of gecko-inspired microfiber surfaces depended on the roughness of the eounterfaces due to the influences of contact area and interlocking mechanism. SEM images of interfaces between counterfaces with different roughness and gecko-inspired mi- crofiber surfaces revealed the matched and dis-matched contact directly. The gecko-inspired microfiber surface got the larger adhesive force from the higher surface energy counterface, which is consisted with Johnson-Kendall-Roberts （JKR） theory. The smaller dimension and lower duty ratio of microfibers on PDMS resulted in the increasing of Water Contact Angle （WCA） and the decreasing of Sliding Angle （SA） compared to those of smooth PDMS. Particularly, sample P-8-28-20 had the biggest WCA （155°） and SA （7°）, which displayed the superhydrophobicity and the best wet self-cleaning efficiency in all samples. The present studies showed that the roughness and surface energy of counterface both affected the adhesion of gecko-inspired microfiber surfaces. The smaller dimension and lower duty ratio of microfibers on PDMS endowed it with the superhydro- phobicity and the wet self-cleaning abilities.

关 键 词：gecko-inspired microfiber polydimethylsiloxane surfaces surface properties counterface SUPERHYDROPHOBICITY wet self-cleaning 

分 类 号：TQ330.16[化学工程—橡胶工业] TG174.4[金属学及工艺—金属表面处理]