Thermal Degradation Kinetics of Structurally Diverse Poly(bispropargyl ethers-bismaleimide) Blends  

作　　者：Jeyaraj Pandiyan Dhanalakshmi Mahendran Arunjunai Raj Chinnaswamy Thangavel Vijayakumar 

机构地区：[1]Department of Chemistry, Kamaraj College of Engineering and Technology, S.P.G.C.Nagar [2]Wood Carinthian Competence Centre, Kompetenzzentrum Holz GmbH [3]Department of Polymer Technology, Kamaraj College of Engineering and Technology, S.P.G.C.Nagar

出　　处：《Chinese Journal of Polymer Science》2016年第3期253-253,254-267,共15页高分子科学（英文版）

基　　金：financially supported by the Management and Principal of Kamaraj College of Engineering and Technology,S.P.G.C.Nagar,K.Vellakulam Post-625701,India for providing all of the facilities to do the work

摘　　要：Structurally diverse bispropargyl ethers using resorcinol,quinol,4,4￠-dihydroxy biphenyl,bisphenol-A,4,4￠-dihydroxy diphenyl ketone,4,4￠-dihydroxy diphenylsulphone,trimethyl indane bisphenol and tetramethyl spirobiindane bisphenol were prepared by using phase transfer catalyst.Synthesized materials were separately blended with 4,4￠-bismaleimido diphenyl methane（BMIM）in mole ratios（0.5：0.5）.The materials were thermally cured and the structural characterisation and the thermal properties of these cross-linked materials are investigated using Fourier-transform infrared（FTIR）spectrophotometer and thermogravimetric analyzer（TGA）.Among the different materials investigated poly MRPE,poly MBPEBPA and poly MSPE show higher onset degradation temperature of 300°C indicating higher thermal stability.The degradation kinetics is investigated using Flynn-Wall-Ozawa（FWO）,Vyazovkin（VYZ）and Friedman（FRD）methods.Amongst the various cured materials investigated,the activation energy（Ea-D）values obtained for poly MRPE and poly MKPE were observed to increase continuously froma=0.2 to 0.8 and the values range from 199 kJ/mol to 245 k J/mol and 153 k J/mol to 295 k J/mol respectively.The crosslinked materials resulting from these bispropargyl monomers definitely need more energy for bond cleavage due to the presence of more aromatic units.The volatile products obtained during the thermal degradation of the polymers were analyzed using thermogravimetric-Fourier transform infrared analyses（TG-FTIR）.The phenols,substituted phenols,carbon monoxide,carbon dioxide and small amount of aniline were found to be the major products during thermal degradation of these cured blends.Structurally diverse bispropargyl ethers using resorcinol,quinol,4,4￠-dihydroxy biphenyl,bisphenol-A,4,4￠-dihydroxy diphenyl ketone,4,4￠-dihydroxy diphenylsulphone,trimethyl indane bisphenol and tetramethyl spirobiindane bisphenol were prepared by using phase transfer catalyst.Synthesized materials were separately blended with 4,4￠-bismaleimido diphenyl methane（BMIM）in mole ratios（0.5：0.5）.The materials were thermally cured and the structural characterisation and the thermal properties of these cross-linked materials are investigated using Fourier-transform infrared（FTIR）spectrophotometer and thermogravimetric analyzer（TGA）.Among the different materials investigated poly MRPE,poly MBPEBPA and poly MSPE show higher onset degradation temperature of 300°C indicating higher thermal stability.The degradation kinetics is investigated using Flynn-Wall-Ozawa（FWO）,Vyazovkin（VYZ）and Friedman（FRD）methods.Amongst the various cured materials investigated,the activation energy（Ea-D）values obtained for poly MRPE and poly MKPE were observed to increase continuously froma=0.2 to 0.8 and the values range from 199 kJ/mol to 245 k J/mol and 153 k J/mol to 295 k J/mol respectively.The crosslinked materials resulting from these bispropargyl monomers definitely need more energy for bond cleavage due to the presence of more aromatic units.The volatile products obtained during the thermal degradation of the polymers were analyzed using thermogravimetric-Fourier transform infrared analyses（TG-FTIR）.The phenols,substituted phenols,carbon monoxide,carbon dioxide and small amount of aniline were found to be the major products during thermal degradation of these cured blends.

关 键 词：Bispropargyl ethers Bismaleimide TG Degradation kinetics TG-FTIR 

分 类 号：O631.5[理学—高分子化学]