Synthesis of aziridines by visible-light induced decarboxylative cyclization of N-aryl glycines and diazo compounds  

Synthesis of aziridines by visible-light induced decarboxylative cyclization of N-aryl glycines and diazo compounds

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作  者:Yong Liu Xichang Dong Guojun Deng Lei Zhou 

机构地区:[1]School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China [2]Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education,College of Chemistry, Xi6ngtan University, Xiangtan 411105, China

出  处:《Science China Chemistry》2016年第2期199-202,共4页中国科学(化学英文版)

基  金:supported by the National Natural Science Foundation of China(21472249;21202207);the Pearl River S&T Nova Program of Guangzhou(2013J2200017);the Fundamental Research Funds for the Central Universities(14lgzd05)

摘  要:A visible-light induced decarboxylative aza-Darzens reaction between N-aryl glycines and diazo compounds was developed, which affords various mono-substituted aziridines in good yields.A visible-light induced decarboxylative aza-Darzens reaction between N-aryl glycines and diazo compounds was developed, which affords various mono-substituted aziridines in good yields.

关 键 词:visible light diazo compound DECARBOXYLATION aza-Darzens reaction 

分 类 号:O626[理学—有机化学]

 

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