O,O＇-(2-甲基-2,4-亚戊基)二硫代磷酸-N,N-二乙铵的合成、表征及缓蚀性能评价  

Synthesis,Characterization,and Corrosion Inhibition of N,N-Diethylammonium O,O'-( 2-Methyl-2,4-pentylene) dithiophosphate

作　　者：魏健[1] 谢斌[1] 赖川[2] 何林芯[1] 李玉龙[1] 邹立科[1] 樊义康 

机构地区：[1]四川理工学院功能材料研究所,材料腐蚀与防护四川省重点实验室,绿色催化四川省高校重点实验室,四川自贡643000 [2]四川文理学院化学化工学院,四川达州635000

出　　处：《应用化学》2016年第2期190-199,共10页Chinese Journal of Applied Chemistry

基　　金：材料腐蚀与防护四川省重点实验室(2012CL12,2014CL14.2015CL09);四川省教育厅(13CZ0019,13ZB0130);自贡市科技局(2012H04);绿色催化四川省高校重点实验室(LYJ1306,LZJ14201,LYJ1503)资助

摘　　要：合成了O,O'-(2-甲基-2,4-亚戊基)二硫代磷酸-N,N-二乙铵(PDP),用元素分析、红外光谱、核磁共振谱和X射线单晶衍射等技术手段对其结构进行了表征。PDP属四方晶系,I-4空间群,其晶胞参数为:a=2.1357(3)nm,b=2.1357(3)nm,c=0.71892(11)nm,α=β=γ=90°,V=3.2791(8)nm3,Z=8,Dc=1.156 g/cm3,F(000)=1232,μ(Mo Kα)=0.412 mm-1,F(000)=1232,S=0.952,R=0.0664,wR=0.1791[I>2σ(I)]。PDP通过NH幆S和CH幆S氢键作用形成了一维超分子孔道结构。PDP在HCl溶液中对Q235钢的缓蚀性研究表明:PDP能有效抑制Q235钢的腐蚀,是阴极为主的混合型缓蚀剂,在Q235钢表面的吸附符合Langmuir吸附,属自发进行的物理化学吸附;在25℃的1.0 mol/L HCl溶液中PDP浓度为140 mg/L时的缓蚀率达到98.9%。CCDC:1404464。A new compound, N,N-diethylammonium O,O＇-（ 2-methyl-2,4-pentylene） dithiophosphate（ PDP）,was synthesized and characterized by elemental analysis,IR,NMR,and X-ray single crystal diffraction analysis. The crystallographic structure analysis reveal that PDP crystallizes in tetragonal system,I-4 space group,a = 2. 1357（ 3） nm,b = 2. 1357（ 3） nm,c = 0. 71892（ 11） nm,α = β = γ = 90°,V =3. 2792（ 10） nm^3,Z = 8,Dc= 1. 156 g / cm^3,F（ 000） = 1232,μ（ Mo Kα） = 0. 412 mm^- 1,F（ 000） = 1232,S = 0. 952,R = 0. 0664,wR = 0. 1791 [I 2σ（ I） ]. One-dimensional channel supramolecular network structure is formed by NH—S and CH—S interactions in the PDP crystal. PDP as a novel corrosion inhibitor for carbon steel in HCl solution was evaluated by mass loss measurement, potentiodynamic polarization,and electrochemical impedance spectroscopy. The results show that PDP acts as a mixed type inhibitor with cathodic inhibition as the dominative action. The adsorption of PDP on carbon steel surface obeys Langmuir isotherm,and the corrosion inhibition belongs to both physi- and chemisorptions. The inhibition efficiency is up to 98. 9% with PDP concentration of 140 mg / L in 1. 0 mol / L HCl solution at 25 ℃.

关 键 词：O O'-亚烷基二硫代磷酸铵 晶体结构 缓蚀性 吸附机理 

分 类 号：O641[理学—物理化学] O646.6[理学—化学]