含咪唑盐的三联吡啶铜配合物的合成和分子结构  

Synthesis and Molecular Structure of Copper Complex of Terpyridine Bearing with Imidazolium Salts

作　　者：穆华荣[1] 毕欣[2] 孙晶[2] 颜朝国[2] 

机构地区：[1]扬州工业职业技术学院化学工程学院,江苏扬州225127 [2]扬州大学化学化工学院,江苏扬州225002

出　　处：《应用化学》2016年第2期206-212,共7页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金基金资助项目(20972132;21301119)~~

摘　　要：通过带有不同长度的4-(4-氯烷氧基苯基)-2,2'∶6,2″-三联吡啶和N-甲基咪唑在甲苯中加热反应,制备了3种由烷氧基桥联的新型三联吡啶咪唑配体。研究了配体和过渡金属离子的配位反应。测定了三联吡啶咪唑铜配合物的单晶分子结构,在铜配合物中,Cu(Ⅱ)和两个三联吡啶单元形成扭曲八面体配位方式。Monoclinic,空间群P 21/c;a=1.7229(3)nm,b=1.5924(2)nm,c=2.1590(3)nm,α=90°,β=101.332(2)°,γ=90°,Mr=1298.09,V=5.8078(15)nm^3,Dc=1.485 mg/m3,Z=4,F(000)=2684。A series of functionalized terpyridine ligands containing alkyl bridged imidazolium salts were designed and prepared in convenient manner. The transition metal complexes of these functionalized terpyridine ligands were investigated and the single crystal structure of Cu complex was successfully determined by X-ray diffraction. In the copper complex,Cu^2 ＋was coordinated with two terpyridine units to form distorted octahedron symmetry. Monoclinic,space group P 21 / c; a = 1. 7229（ 3） nm,b = 1. 5924（ 2） nm,c =2. 1590（ 3） nm,α = 90°,β = 101. 332（ 2） °,γ = 90°,Mr= 1298. 09,V = 5. 8078（ 15） nm^3,Dc=1. 485 mg / m^3,Z = 4,F（ 000） = 2684.

关 键 词：三联吡啶 咪唑盐 金属配合物 晶体结构 

分 类 号：O626.3[理学—有机化学]