2,6-二氨基-3,5-二硝基吡啶-1-氧化物Fe(Ⅲ)和Co(Ⅲ)含能配合物的燃烧催化性能  

Combustion Catalytic Performance of Energetic Fe( Ⅲ) and Complexes Derived From 2,6-Diamino-3,5-dinitropyridine-1-oxide

作　　者：刘进剑[1] 刘祖亮[2] 成健[2] 

机构地区：[1]山西师范大学化学与材材科学学院,山西临汾041004 [2]南京理工大学化工学院,江苏南京210094

出　　处：《含能材料》2016年第2期161-165,共5页Chinese Journal of Energetic Materials

摘　　要：采用密闭爆发器实验和靶线法实验测试了2,6-二氨基-3,5-二硝基吡啶-1-氧化物（ANPyO）的Fe（Ⅲ）和Co（Ⅲ） 配合物作为燃烧催化剂的可行性。结果表明,两种配合物对发射药的燃烧催化效果明显,提高了燃速,并使压力指数降低2.97%～11.36%; Fe（Ⅲ）配合物在10～20 MPa压强范围内使双基推进剂的燃速提高20%以上,并使压力指数在10,14,18,20 MPa 4个压强点降低25.30%～45.78%,催化效果良好; Co（Ⅲ）配合物对双基推进剂燃烧的催化效果不明显。The feasibility of Fe（Ⅲ） and Co（Ⅲ） energetic complexes of 2,6-diamino-3,5-dinitropyridine-1-oxide （ANPyO） as combustion catalysts was tested by closed bomb test and target lines experiment. Results show that the two complexes have obvious catalytic effects on the combustion of double-base gun propellants and triple-base gun propellants by increasing of the burning rate and decreasing of the pressure exponent by 2.97%-11.36%. The Fe（Ⅲ） complex has significant catalytic effects on the combustion of double-base propellants with the burning rate increasing by more than 20% in the pressure range of 10-20 MPa and the pressure index decresing by 25.30%-45.78% at 10,14,18,20 MPa,respectively. While, the catalytic effect of Co（Ⅲ） complex on double-base propellant is not obvious.

关 键 词：2 6-二氨基-3 5-二硝基吡啶-1-氧化物(ANPyO) 含能配合物 燃烧催化剂 发射药 双基推进剂 

分 类 号：TQ560.1[化学工程—炸药化工]