间歇精馏分离甲基苯基二乙氧基硅烷  

Purification of Methylphenyldiethoxysilane by Batch Distillation

作　　者：华超[1] 叶佳义 陆平[1] 王文忠[1] 刘会州[1] 刘艳[1] 王炳帅 姜艳 

机构地区：[1]中国科学院过程工程研究所绿色过程与工程重点实验室,北京100190 [2]辽宁科隆精细化工股份有限公司,辽宁辽阳111003

出　　处：《过程工程学报》2016年第1期105-109,共5页The Chinese Journal of Process Engineering

基　　金：国家重点基础研究发展规划(973)基金资助项目(编号:2013CB632602);国家自然科学基金青年科学基金资助项目(编号:21306198);国家高技术研究发展计划(863)基金资助项目(编号:2013AA030705)

摘　　要：以间歇精馏法提纯甲基苯基二乙氧基硅烷合成液,采用化工模拟软件Aspen Plus 7.0建立了工艺流程模型.结果表明,在常压下先预分离回收氯苯和甲基三乙氧基硅烷,在5 k Pa、回流比R=3条件下提纯甲基苯基二乙氧基硅烷,产品纯度为99.67%,单程收率为70.56%,证明了间歇精馏分离甲基苯基二乙氧基硅烷工艺的可行性.模拟结果与实验结果相对误差小于8%,为甲基苯基二乙氧基硅烷提纯工艺的工业放大提供了必要的基础数据.Separation of methylphenyldiethoxysilane from synthetic fluid was carried out by batch distillation, meanwhile the process was simulated with Aspen Plus 7.0 software. The results showed that chlorobenzene and methyltriethoxysilane were pre-separated under atmospheric pressure, then methylphenyldiethoxysilane was purified under the pressure of 5 k Pa and reflux ratio at 3, the resulting product had the purity of 99.67% with the single pass yield of 70.56%. The feasibility of methylphenyldiethoxysilane separation process by batch distillation was verified by experiments and simulation model with Aspen Plus 7.0 as well. The relative error between simulation and experimental result was less than 8%, which could provide basic data for industrialization.

关 键 词：甲基苯基二乙氧基硅烷 精馏 模拟 分离 氯苯 甲基三乙氧基硅烷 

分 类 号：O633.2[理学—高分子化学]