AgNbO_3/石墨烯复合材料的合成及其可见光催化甲基橙降解活性（英文）  

Synthesis of AgNbO_3/Graphene Nanocomposites with Highly Visible Light Photocatalytic Activity for Removal of Methyl Orange

作　　者：苗慧[1,2,3] 夏娟[1] 金凤[1,2] 孙林[1,2] 崔玉民[1,2] 李慧泉[1,2] 丁建[1] 

机构地区：[1]阜阳师范学院化学与材料工程学院,安徽阜阳236037 [2]安徽环境污染物降解与监测省级实验室,安徽阜阳236037 [3]功能性分子固体省部共建教育部重点实验室,安徽芜湖241000

出　　处：《发光学报》2016年第2期165-173,共9页Chinese Journal of Luminescence

基　　金：国家自然科学基金(21402029;21401024);安徽省高校青年人才基金(2013SQRL058ZD);安徽省自然科学基金(1408085MB35);安徽省高校自然科学基金(KJ2014A191)资助项目

摘　　要：采用固相法合成AgNbO_3/石墨烯复合纳米材料,利用透射电子显微镜(TEM)及紫外-可见漫反射光谱(UV-Vis)对样品的形貌及光学性质进行了表征。研究发现,AgNbO_3与石墨烯复合后,带隙能明显降低,吸收光波长范围增大。以甲基橙溶液的降解为光催化模型反应评价了AgNbO_3/石墨烯复合纳米材料的可见光催化性能。结果表明:与纯AgNbO_3相比,AgNbO_3/石墨烯复合纳米材料对甲基橙的可见光催化性能明显增强。实验条件下,经300℃煅烧的AgNbO_3/石墨烯(2∶1)复合纳米材料表现出最优的催化性能,它对甲基橙的可见光催化脱色速率系数约为纯AgNbO_3的10倍。光催化降解机理研究表明,促使甲基橙降解脱色的主要活性物种为·O_2^-和h+。AgNbO3/graphene nanocomposites were synthesized via the technique of solid-solid grinding and subsequent sintering process. Surface structures and optical properties of the prepared materials were characterized by transmission electron microscopy and UV-Vis diffuse reflection spectroscopy. The results indicate that band-gap of AgNbO3 is lowered upon eompositing with graphene nanoparticles, thereby giving an absorption in a large range of wavelengths. Degradation of methyl orange （MO） is carried out to evaluate the photocatalytic activity of AgNbO3/graphene nanocomposites under visible light irradiation. Compared with pure AgNbO3 , AgNbO3/graphene composites exhibit significantly enhanced photocatalytie activity for MO. Moreover, AgNbO3/graphene （2：1 ） obtained at 300 ℃ exhibits the highest degradation degree of MO after an irradiation of 120 min with apparent kapp of 0. 034 min-1, which is about 10 times than that of the pure AgNbO3. The tests of radical scavengers confirm that O2- and h＋ are the main reactive species for the degradation of MO.

关 键 词：固相法 AgNbO3/石墨烯纳米材料 可见光催化 降解 甲基橙 

分 类 号：O634[理学—高分子化学]