镍氢电池负极材料V2Ti0.5Cr0.5Ni1-xMox（x=0.02~0.08）的结构和电化学性能  

Structures and Electrochemical Properties of V_2Ti_(0.5)Cr_(0.5)Ni_(1-x)Mo_x(x=0.02-0.08) Ni/MH Battery Anode Materials

作　　者：同艳维[1] 张雪峰[2] 方民宪[2] 

机构地区：[1]攀枝花学院生物与化学工程学院,攀枝花617000 [2]攀枝花学院资源与环境工程学院,攀枝花617000

出　　处：《无机材料学报》2016年第2期148-152,共5页Journal of Inorganic Materials

基　　金：四川省教育厅科研项目(15ZB0426);攀枝花市科技项目(2015CY-S-11);钒钛资源综合利用四川省重点实验室项目(VTZ-2015003)~~

摘　　要：为了改善镍氢电池负极材料的循环稳定性能,采用真空感应电弧熔炼炉制备了V2Ti0.5Cr0.5Ni1-xMox（x=0.02~0.08）合金,分析了不同含量的Mo替代Ni之后对合金电极的组织结构及电化学性能的影响。研究结果表明,电极材料主要由BCC结构的V基固溶体主相和Ti Ni二次相组成,随着合金中Mo替代Ni含量x由0.02增加到0.08,合金电极的放电容量先增加后降低,合金电极的循环稳定性能以及电化学动力学性能先得到改善而后降低,合金电极的综合性能均在x=0.04时达到最好。In order to improve the cycle stability of Ni/MH battery, the V2Ti0.5Cr0.5Ni1-xMox（x=0.02~0.08） electrode alloys were prepared by arc-melting, and the effects of Mo content On microstructure and electrochemical properties were investigated systematically. The results show that all of the electrode materials mainly consist of a V-based solid solution phase with BCC structure and TiNi-based secondary phase which precipitates along the grain bound- ary of the BCC main phase. The electrochemical measurements indicate that the maximum discharge capacity of the alloy electrode increases firstly and then decreases with increasing x from 0.02 to 0.08. The cycle stability and elec- trochemical kinetic response of the alloy electrodes are strengthened firstly and then weakened, and reach the best performance at x=0.04.

关 键 词：镍氢电池 负极材料 循环稳定性 电化学性能 

分 类 号：TG146[一般工业技术—材料科学与工程]