抗高温油基钻井液主乳化剂的合成与评价  

Synthesis and Evaluation of A Primary Emulsifier for High Temperature Oil Base Drilling Fluid

作　　者：覃勇[1] 蒋官澄[2] 邓正强[2] 葛炼[1] 

机构地区：[1]川庆钻探工程有限公司钻井液技术服务公司,成都610051 [2]中国石油大学(北京),北京102200

出　　处：《钻井液与完井液》2016年第1期6-10,共5页Drilling Fluid & Completion Fluid

基　　金：中国石油天然气集团公司重大科技专项"复杂地质条件钻井液技术研究"(CQ2013B-39-2-3)

摘　　要：以妥尔油脂肪酸和马来酸酐为主要原料合成了一种油基钻井液抗高温主乳化剂HT-MUL,并确定了妥尔油脂肪酸单体的最佳酸值及马来酸酐单体的最优加量对HT-MUL进行了单剂评价,结果表明HT-MUL的乳化能力良好,配制的油水比为60:40的油包水乳液的破乳电压最高可达490 V,90:10的乳液破乳电压最高可达1 000 V,从抗温性、滤失性、乳化率方面对HT-MUL和国内外同类产品进行了对比,结果表明HT-MUL配制的乳液破乳电压更大、滤失量更小、乳化率更高,整体性能优于国内外同类产品,应用主乳化剂HT-MUL配制了高密度的油基钻井液,其性能评价表明体系的基本性能良好,在220℃高温热滚后、破乳电压高达800 V,滤失量低于5 mL HT-MUL配制的油基钻井液具有良好的抗高温性和乳化稳定性。A primary emulsifier, HT-MUL, for high temperature oil base drilling fluid was developed using tall oil fatty acids and maleic anhydride, and the optimum acid value of tall oil fatty acids and optimum concentration of maleic anhydride for the reaction were determined. Evaluation of HT-MUL shows that HT-MUL performs very well as an emulsifier. Using HT-MUL, a water-in-oil emulsion （O/W ratio = 60 ： 40） was formulated, having electrical stability of 490 V, and another water-in-oil emulsion （O/W ratio = 90 ： 10）, having electrical stability of 1,000 V. Comparison of HT-MUL with other primary emulsifiers demonstrates that emulsions formulated with HT-MUL have higher electrical stability voltage, lower filter loss and higher rate of emulsion, proving that HT-MUL has better general performance than other emulsifiers. A high performance high density oil base drilling fluid was formulated using HT-MUL, retaining electrical stability of 800 V and filter loss less than 5 mL after hot rolling at 220 ℃. Oil base drilling fluids formulated with HT-MUL have good high temperature performance and emulsion stability.

关 键 词：抗高温 油基钻井液 主乳化剂 

分 类 号：TE254.4[石油与天然气工程—油气井工程]