直接法硝解乌洛托品制备黑索今机理研究进展  

Research progress in nitrolysis mechanism during RDX preparation by direct nitration

作　　者：李静[1] 张天贝 兰贯超 侯欢[1] 李满[1] 

机构地区：[1]中北大学化工与环境学院,山西太原030051

出　　处：《应用化工》2016年第2期345-349,共5页Applied Chemical Industry

基　　金：国防产品创新项目

摘　　要：直接法制备黑索今的硝解机理研究一直是炸药领域备受关注的一项研究,硝解机理的明确直接关系着直接法制备黑索今的工艺研究进展,关系着黑索今得率的提高,以致于从根本上将黑索今的硝解工艺发展成为一项经济型工艺。从有机反应的机理分析中应用较多的理论研究、中间体研究、产物研究、同位素研究以及反应条件研究等介绍了直接法硝解乌洛托品制备黑索今机理研究现状与进展,并指出在线仪器及新型技术的使用将成为该项研究的发展趋势。The research of nitrolysis mechanism during RDX preparation by direct nitration has been a great concern in the field of explosives. The clearly nitrolysis mechanism is directly connected with the progress of RDX synthesis and the yield of RDX, which may fundamentally develop the preparation of RDX to be an economical process. The studies of theory, intermediates, products, isotope and reaction conditions which are mostly applied in organic reaction are introduced aiming at explaining the current situa- tions and progress of nitrolysis mechanism in direct nitration of urotropine. It is pointed out that the use of online instruments and new technology will become the development trend for this research in the future.

关 键 词：直接法 乌洛托品 黑索今 机理 

分 类 号：TQ564[化学工程—炸药化工] TJ55[兵器科学与技术—军事化学与烟火技术]