钼磷硼改性酚醛树脂性能的研究  

Mechanical Properties of Molybdenum,Phosphorus and Boron Modified Phenolic Resin

作　　者：李燕琳[1] 尹育航[1,2] 薛群虎[1] 杨玉鹤[1] 

机构地区：[1]西安建筑科技大学材料与矿资学院,西安710055 [2]广东奔朗新材料股份有限公司,佛山528313

出　　处：《硅酸盐通报》2016年第2期665-669,共5页Bulletin of the Chinese Ceramic Society

摘　　要：按照正交试验法制备不同钼磷硼含量的改性热塑性酚醛树脂,以分子量为检测指标,选出最优方案,并利用红外光谱法、热重分析等方法对其结构进行研究。实验结果表明:以苯酚质量为基准,当钼酸铵、磷酸、硼酸的含量为1%、1%、5%时为较优配方,此时改性酚醛树脂的热分解温度为499℃,700℃的残炭率为52.3%,抗弯强度达到58.12 MPa,冲击强度达到0.27 J/cm2。According to the orthogonal test method, preparation of modified thermoplastic phenolic resin with different molybdenum, phosphorus and boron contents has been investigated. Products were subjected to IR spectrum, TG, etc, with molecular weight as the test index to select an optimal formula. Experimental results show that ： it is a better formula with the content of （ NH4 ） 2 MoO4, H3 PO4, H3 BO3 is 1%, 1%, 5% based on the mass of phenol, when its thermal decomposition temperature is 499 ℃, residue carbon rate at 700℃ is 52.3% , bending strength is 58.12 MPa and impact strength is 0.27 J/cm2 .

关 键 词：正交试验法 改性热塑性酚醛树脂 分子量 热分解温度 残炭率 

分 类 号：TQ322[化学工程—合成树脂塑料工业]