A novel method to anchor methanesulfonic acid in silica matrix  

作　　者：Naiwang Liu Jiajia Yao Li Shi 

机构地区：[1]State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China

出　　处：《Science China Chemistry》2016年第3期370-379,共10页中国科学（化学英文版）

摘　　要：Methanesulfonic acid （MSA） was successfully immobilized in silica, leading to a novel and environmentally friendly solid acid catalyst SMSA. The most important feature of SMSA is that anhydrous formic acid is used to hydrolysis of tetraethylorthosili- cate （TEOS）. No water was added in the whole preparation. Therefore, MSA could be anchored in silica matrix more effec- tively instead of being dissolved in water. This new organic/inorganic hybrid catalyst was characterized by powder X-ray dif- fraction （XRD）, energy dispersive spectrum （EDS）, N2 adsorption-desorption analyzer, thermogravimetric analysis （TGA-DSC） and pyridine-FTIR. The catalytic activity was tested by alkylation of olefins and aromatics. High concentration acid sites, both Lewis and Brcnsted, abundant porosity and large surface area enabled the highest activity for SMSA, among MCM-22. ZSM-5 and industrial acidity clay.Methanesulfonic acid(MSA) was successfully immobilized in silica, leading to a novel and environmentally friendly solid acid catalyst SMSA. The most important feature of SMSA is that anhydrous formic acid is used to hydrolysis of tetraethylorthosilicate(TEOS). No water was added in the whole preparation. Therefore, MSA could be anchored in silica matrix more effectively instead of being dissolved in water. This new organic/inorganic hybrid catalyst was characterized by powder X-ray diffraction(XRD), energy dispersive spectrum(EDS), N_2 adsorption-desorption analyzer, thermogravimetric analysis(TGA-DSC) and pyridine-FTIR. The catalytic activity was tested by alkylation of olefins and aromatics. High concentration acid sites, both Lewis and Br?nsted, abundant porosity and large surface area enabled the highest activity for SMSA, among MCM-22, ZSM-5 and industrial acidity clay.

关 键 词：methanesulfonic acid olefin removal solid acid catalyst ALKYLATION 

分 类 号：O643.36[理学—物理化学]