A Cd(Ⅱ)Coordination Polymer with cds Topology Constructed by Polycarboxylate and Imidazole-containing Ligand  

作　　者：张美丽 高娜 高楼军 

机构地区：[1]Shaanxi Key Laboratory of Chemical Reaction Engineering,Yan'an University

出　　处：《Chinese Journal of Structural Chemistry》2016年第1期143-149,共7页结构化学（英文）

基　　金：supported by the Natural Science Foundation of Yan’an University(YD2014-06);the Natural Scientific Research Foundation of Yan’an City Technology Division(2014ZC-3);the Provincial College Students’Innovation and Entrepreneurship Training Program(1452)

摘　　要：A new Cd（Ⅱ） coordination polymer,{[Cd（pda）（bimb）]·（H2O）（0.5）}n（1,H2pda=1,3-phenylenediacetic acid,bimb = 4,4-bis（1-imidazolyl）biphenyl）,has been synthesized and characterized by elemental analysis,IR spectroscopy,powder X-ray diffraction（PXRD） analyses and single-crystal X-ray diffraction techniques. Complex 1 shows a 4-connected two-fold interpenetrated three-dimensional（3-D） cds topology. In additional,photoluminescent properties of 1 and its dehydrated product have also been studied.A new Cd（Ⅱ） coordination polymer,{[Cd（pda）（bimb）]·（H2O）（0.5）}n（1,H2pda=1,3-phenylenediacetic acid,bimb = 4,4-bis（1-imidazolyl）biphenyl）,has been synthesized and characterized by elemental analysis,IR spectroscopy,powder X-ray diffraction（PXRD） analyses and single-crystal X-ray diffraction techniques. Complex 1 shows a 4-connected two-fold interpenetrated three-dimensional（3-D） cds topology. In additional,photoluminescent properties of 1 and its dehydrated product have also been studied.

关 键 词：coordination polymer synthesis crystal structure luminescent properties 

分 类 号：O634[理学—高分子化学]