新型含芴基的富勒烯衍生物的合成  

Synthesis of Novel [60]Fullerene Derivatives Containing Fluorene

作　　者：韩露[1] 刘奉丽[1] 丁敏源 徐昱捷 李慧[1] 

机构地区：[1]华东理工大学材料科学与工程学院,上海200237

出　　处：《合成化学》2016年第3期219-222,共4页Chinese Journal of Synthetic Chemistry

基　　金：科技部国际合作项目(2010DFB70470)

摘　　要：以2,7-二溴芴酮为起始原料,经Suzuki偶合、腙化和1,3-偶极环反应合成了3种新型的含芴基的富勒烯衍生物,其结构经UV-Vis,1H NMR,13C NMR,FT-IR和MALDI-TOF-MS表征。Three novel [60]fullerene derivatives containing fluorene were synthesized by Suzuki coupling reaction,hydrazone reaction and 1,3-dipolar cycloaddition reaction,using 2,7-dibromofluoren-9-one as the starting material. The structures were characterized by UV-Vis,1H NMR,13 C NMR,FT-IR and MALDI-TOF-MS.

关 键 词：富勒烯 SUZUKI 1 3-偶极环加成反应 合成 

分 类 号：O613.71[理学—无机化学] O621.3[理学—化学]