Anderson型双亲催化剂(C_(21)H_(46)N)_3[CoMo_6O_(24)H_6]的制备及其应用  

The Preparation and Applications of the Anderson-Type Amphiphilic Catalyst (C_(21)H_(46)N)_3[CoMo_6O_(24)H_6]

作　　者：柴学磊 赵阳[1] 孙晨晨[1] 

机构地区：[1]西安石油大学石油炼化工程技术研究中心,陕西西安710065

出　　处：《广东化工》2016年第6期8-10,共3页Guangdong Chemical Industry

基　　金：西安石油大学2014年全日制硕士研究生创新基金资助项目(2014cx130740)

摘　　要：利用一系列含硫量为500 ppm的模型化合物进行了研究。合成了一系列Anderson型双亲催化剂(C_(21)H_(46)N)_3[CoMo_6O_(24)H_6],在H_2O_2/(C_(21)H_(46)N)_3[CoMo_6O_(24)H_6]体系下研究了影响氧化脱硫效果的因素,并结合实验结果进行了分析。通过实验探索出十八烷基三甲基氯化铵是最合适的表面活性剂;水乙醇相合成的(C_(21)H_(46)N)_3[CoMo_6O_(24)H_6]在反应2 h后二苯并噻吩的脱硫率可以达到92.68%。红外光谱分析结果表明:H_2O_2/(C_(21)H_(46)N)_3[CoMo_6O_(24)H_6]体系可以将油品中的噻吩类硫化物氧化成相应的砜或者亚砜。In the paper, a series of model compounds were used with the sulfur content of 500 ppm. Anderson type amphiphilic catalyst（C_（21）H_（46）N）_3[CoMo_6O_（24）H_6] was synthesized. and used as a catalyst to study the oxidative desulfurization of the sulfur-containing compounds. The experimental results show that Octadearyl dimethyl ammonium chloride is the most appropriate surfactant;（C_（21）H_（46）N）_3[CoMo_6O_（24）H_6] synthesized in the water-ethanol is the best preparation methods. The DBT conversion value can reach 92.68 % in reaction for 2 h. Infrared spectrum analysis results showed： in the H_2O_2/（C_（21）H_（46）N）_3[CoMo_6O_（24）H_6] system the sulfide compounds in oils could be oxidized into the corresponding sulfones.

关 键 词：杂多酸 Anderson型催化剂 氧化脱硫 

分 类 号：TQ424.2[化学工程]