椰壳活性炭孔结构对Li-S电池性能的影响  

Effect of Pore Structure of the Coconut Shell Activated Carbon on the Performance of Li-S Batteries

作　　者：张娜[1] 刘敏[1] 陈永[1] 

机构地区：[1]海南大学材料与化工学院,热带生物资源教育部重点实验室,热带岛屿资源先进材料教育部重点实验室,硅锆钛资源综合开发与利用海南省重点实验室,海口570228

出　　处：《材料导报》2016年第6期52-55,共4页Materials Reports

基　　金：国家自然科学基金(51162006,51362009);海南省国际科技合作专项(KJHZ2015-02);海南省重点项目(ZDXM2015118);中西部计划学科重点建设(ZXBJH-XK009)

摘　　要：以椰壳为原料,采用化学活化法制备不同比表面积和孔结构的活性炭,通过改变制备工艺参数来调节活性炭的比表面积和孔结构。将活性炭负载60%(质量分数)硫后,作为锂硫电池的正极材料,研究活性炭孔结构对锂硫电池性能的影响。结果表明:随着活性炭比表面积的增加,中孔比例增加,锂硫电池比容量逐步提高。其中,当活化剂与炭化料的质量比为4时,活性炭的比表面积达到2900m2/g,中孔率达到15.36%。在电流密度为200mA/g时,首次放电比容量高达1294.5mAh/g,循环100次后的可逆比容量仍然高达809.3mAh/g。Coconut shell-based activated carbon with different surface area and pore structure was prepared through the chemical activation, which was then composited with sulfur and used as the cathode materials for lithiumsulfur batteries. Experimental results showed that the specific capacity was gradually increased with increasing the surface area and the proportion of mesoporous in activated carbon. When weight ratio between activator and carbon materials was 4, the activated carbon had a high surface area of 2900 m^2/g and a proportion of mesopores of 15. 36%. And the initial specific capacity of batteries was 1294. 5 mAh/g at a current density of 200 mA/g and retained 809. 3 mAh/g after 100 cycles which showing good cycling performance.

关 键 词：活性炭 孔结构 锂硫电池 电化学性能 

分 类 号：TM912.9[电气工程—电力电子与电力传动]