基于主-客体作用的超分子聚合物的构筑和调控进展  

Recent Progress in the Construction and Regulation of Supramolecular Polymers Based on Host-Guest Interactions

作　　者：黄文忠[1] 占田广 林沨 赵新[2] 

机构地区：[1]昆明学院化学科学与技术系,昆明650214 [2]中国科学院上海有机化学研究所,上海200032

出　　处：《化学进展》2016年第2期165-183,共19页Progress in Chemistry

基　　金：国家自然科学基金项目(No.21472225);云南省科技厅省应用基础研究计划项目(No.2013FZ103);昆明学院科研创新团队建设项目(No.2015CXTD03)资助~~

摘　　要：超分子聚合物是超分子化学与高分子科学交叉而产生的一个新的研究领域。在超分子聚合物中单体之间主要依靠非共价作用如氢键、金属配位、主-客体作用等来连接。这其中,利用主-客体作用驱动组装的超分子聚合物是这一领域的重要代表。本文在简要介绍超分子聚合物的概念和历史的基础上,着重总结了近几年来基于主-客体化学构筑超分子聚合物的一些代表性进展,根据主体分子结构的不同分为基于冠醚/穴醚、环糊精、杯芳烃、葫芦脲和柱芳烃的超分子聚合物五个部分,最后对该领域目前的研究现状以及今后的主要发展方向进行了总结和展望。Supramolecular polymer is a new interdiscipline of supramolecular chemistry and polymer science. In supramolecularly polymeric structures the monomers are connected by noncovalent bonds such as hydrogen bonds,metal-organic coordinations,and host-guest interactions and so on. Supramolecular polymers constructed on the basis of host-guest interactions constitute of a main branch of the whole family of supramolecular polymers. In this review,some representative progress on the construction of supramolecular polymers based on host-guest interactions has been summarized, after a brief introduction of the concept and history of supramolecular polymer. It has been divided into five parts according to the different structures of the host molecules. In the last part,the challenges and prospective tendency of this subject have also been discussed.

关 键 词：主-客体作用 超分子聚合物 大环 自组装 

分 类 号：O631[理学—高分子化学] O641.3[理学—化学]