稳定同位素标记硼氘化钠的合成  

Synthesis of Isotope-labeled Sodium Borohydride-D4

作　　者：谭树波[1] 杨维成[1] 罗勇[1] 

机构地区：[1]上海化工研究院上海稳定同位素工程技术研究中心,上海200062

出　　处：《化学试剂》2016年第4期311-313,360,共4页Chemical Reagents

基　　金：科技部转制院所专项(2014EG116258);上海张江国家自主创新示范区专项项目(201411-PT-C101-013)

摘　　要：通过对硼氢化钠的合成方法研究,确定了同位素标记硼氘化钠的制备方法:以硼砂、金属钠、氘气为原料,搅拌下将反应釜升温至450℃,反应0.5 h,得含硼氘化钠产品的粗砂,采用索氏提取法处理粗砂,得目标产物硼氘化钠产品,产品纯度99.2%,同位素丰度99.9 atom%D。The synthesis procedure of isotope-labeledsodium borohydride-D4 was investigated via changing different parameters and established finally. The reaction system which had been added sodium tetraborate,sodium and deuterium gas was firstly heated up to 450 ℃ with stirring and kept for 0. 5 h. The raw product was then extracted with soxhlet extractor,the purity of the target product was 93. 7%,and D abundance of sodium borohydride-D4 was 99. 9 atom% D.

关 键 词：硼砂 硼氘化钠 同位素标记 合成 

分 类 号：O611[理学—无机化学]