乙烯-1-己烯共聚物多元序列结构的定量研究  

Quantitative analysis of multi-sequence distributions in poly(ethylene-co-hexene)

作　　者：高凌雁[1] 王群涛[1] 郭锐[1] 唐岩[1] 侯斌[1] 裴小静[1] 

机构地区：[1]中国石油化工股份有限公司齐鲁分公司研究院,山东省淄博市255400

出　　处：《合成树脂及塑料》2016年第2期55-58,共4页China Synthetic Resin and Plastics

摘　　要：通过分析"塑料线型低密度聚乙烯组成的定量分析碳-13核磁共振谱法(SH/T 1775—2012)",得出了一种与标准区间划分相同而且可以计算乙烯-1-己烯共聚物多元序列结构含量的方法,通过与国外计算方法进行实例对比从而验证其合理性。结果表明:采用该方法计算出共聚单体含量和支化点个数后可以直接用同样的区间划分来计算序列结构含量;而且既可以直接计算多元序列结构含量,更加直观地表达乙烯链段的链接方式,又可以计算三元序列结构含量;该方法与国外计算方法差别不大。A calculation method is obtained with the help of the standard of SH/T 1775-2012, i.e., quantitative analysis of plastics linear low density polypropylene by carbon-13 nuclear magnetic resonance spectroscopy, which is in accordance with collective assignment regions and can be used for calculating the multi-sequence distributions in poly（ethylene-co-hexene）. Moreover, the method is verified by comparing with foreign calculation methods. The results show that this method can directly calculate the multi-sequence distributions after calculating the comonomer and branch points,it not only can calculate the multi-sequence distributions to express the carbon construction intuitively but also be converted into ternary structure. It proves to be similar with those foreign calculation methods.

关 键 词：乙烯-1-己烯共聚物 多元序列结构 定量研究 共聚单体 

分 类 号：O631.1[理学—高分子化学]