生物质转化制备重要平台化合物γ-戊内酯的研究进展  

Advances in Conversion of Biomass to Renewable Platform Molecule γ-Valerolactone

作　　者：朱龙云[1] 杨文霞 刘迎新[1] 

机构地区：[1]浙江工业大学药学院,浙江杭州310014 [2]山东铁雄冶金科技有限公司,山东邹平256200

出　　处：《浙江化工》2016年第3期20-26,共7页Zhejiang Chemical Industry

基　　金：国家自然科学基金项目(No.21476211)

摘　　要：将自然界数量巨大且价廉易得的可再生资源生物质转化为高附加值的平台化合物是生物质资源综合利用领域的研究热点。生物质基γ-戊内酯即是一种重要的平台化合物,可由生物质经水解、加氢、脱水得到。本文就近年来由生物质及其衍生物乙酰丙酸制备γ-戊内酯的研究进展进行了综述,对所用的催化剂和反应体系进行了总结,以期寻求一种高效、经济的γ-戊内酯合成路径。The conversion of biomassinto high value-added platform chemicals has received sharply increasing interest in academia and industry. Biomass-derived γ-valerolactone is one of the renewable platform chemicals, which can be produced in a sequential tandem process by hydrolysis of biomass and subsequent hydrogenation of the hydrolysis products. In this review, recent research progresses for the production of GVL from biomass were summarized in view of catalysts and reaction systems. And the future research trends of GVL were suggested.

关 键 词：生物质 乙酰丙酸 加氢 γ-戊内酯 

分 类 号：O623.624[理学—有机化学]