十二烯基琥珀酸淀粉酯的合成及其应用研究  

Synthesis of Dodecenly Succinic Starch Ester and Its Application Research

作　　者：刘瑞帆 安会勇[1] 徐昆[2] 张文德[2] 谭颖[2] 王明权[2] 

机构地区：[1]辽宁石油化工大学,辽宁抚顺113001 [2]中国科学院长春应用化学研究所,吉林长春130022

出　　处：《造纸科学与技术》2016年第1期38-42,共5页Paper Science & Technology

基　　金：浙江省科技发展计划科技特派员专项项目资助(20131232i37)

摘　　要：以氢氧化钠为催化剂,十二烯基琥珀酸酐(DDSA)为酯化剂,十二烷基苯磺酸钠为相转移剂,在水介质中成功的制备了十二烯基琥珀酸淀粉酯(SSDS)。分别研究了反应时间、反应温度、p H值和DDSA用量对SSDS取代度的影响。研究结果表明,当淀粉乳质量浓度为30%,反应时间5 h,反应温度40℃,p H=9.0,DDSA添加量为3%,制备的SSDS取代度可达到0.0168。采用FTIR和1H NMR证实了SSDS的结构。污泥回用抄纸实验表明,SSDS的加入可显著提高添加污泥的再生纸张的环压性能。Dodecenly succinic starch ester（ SSDS） was successfully synthesized in aqueous using sodium hydroxide and sodium dodecyl benzene sulfonate as catalyst and phase transfer,respectively. The effects of reaction time,temperature,p H and dodecenly succinic anhydride dosage on the degree of substitution（ DS） of cationic starch were investigated in detail. The results indicated that the DS of SSDS was 0. 0168 when the starch concentration,reaction time,temperature,p H and dodecenly succinic anhydride dosage were 30% wt,5h,40℃,9 and 3% wt,respectively. The macromolecular structure of SSDS was also confirmed by FTIR and1 HNMR characterizations. The papermaking sludge reusing experiment showed that the SSDS could effectively improve the ring crush strength of paper added papermaking sludge.

关 键 词：十二烯基琥珀酸淀粉酯 取代度 污泥回用 环压强度 

分 类 号：TS79[轻工技术与工程—制浆造纸工程]