一种新型双核钴酞菁的制备及其表征  

Preparation and characterization of a novel binuclear cobalt phthalocyanine

作　　者：尹彦冰[1] 张浩[1] 宫晶[1] 

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006

出　　处：《高师理科学刊》2016年第3期29-31,共3页Journal of Science of Teachers＇College and University

基　　金：黑龙江省普通高校新世纪优秀人才培养计划项目(1154-NCET-014)

摘　　要：合成了双核酞菁的前体化合物2,2-二[4-二(3,4-二腈基苯氧基)苯基]丙烷,以其与4-硝基邻苯二腈、硝酸钴在融熔状态下合成了一种新型双核钴酞菁配合物.通过红外、紫外、核磁及热质量等手段对前体及目标产物进行了表征.红外、核磁表征验证了前体结构式与理论相符,紫外光谱的Q带和B带反映了配合物的碳骨架结构,热质量分析表明,该配合物在氮气中拥有较高的热稳定性.A novel binuclear cobalt phthalocyanin is synthetised in the condition of melting which is used 2,2-di[4-di（3,4）-dicyanophenyl] Propane,nitry l phthalic nitrile and metal-salt.The product of precursor and target were characteristiced by IR,UV-VIS,1HNMR and TG method.The characteristised by IR and 1HNMR were verified that precursor formula was consistented with the theory,the carbon skeleton structure of the complexes can be reflected by the UV spectrum of Q-band and B-band,thermal mass analysis showed that the complexes had higher thermal stability in nitrogen.

关 键 词：双核钴酞菁 合成 表征 

分 类 号：O621.3[理学—有机化学]