A Cobalt Supramolecular Compound Constructed from 4,6-Di（1-imidazolyl）- 1,3,5-triazine-2-one： Synthesis, Characterization and Magnetic Property  

作　　者：ZHENG Tianxing HAN Yide LIU Ningning 

机构地区：[1]College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, P. R. China [2]Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, P. R. China

出　　处：《Chemical Research in Chinese Universities》2016年第2期184-187,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（Nos.21204034, 21301024） and the Fundamental Research Funds for the Central Universities of China（No.N120305003）.

摘　　要：A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca（No.73） with a=1.80696（12） nm, b=1.93224（11） nm, c=1.36798（10） nm, V=4.7763（5） nm3 and R1=0.0438. Compound 1 is a 3D supramolecular architecture composed of 1D wave-like chains with hydrogen bonds and π-π interactions. Compound 1 was further characterized by powder X-ray diffraction（PXRD）, infrared（IR） spectroscopy, thermogravimertic analysis（TG） and elemental analysis. Additionally, the magnetic property of compound 1 was also investigated.A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca（No.73） with a=1.80696（12） nm, b=1.93224（11） nm, c=1.36798（10） nm, V=4.7763（5） nm3 and R1=0.0438. Compound 1 is a 3D supramolecular architecture composed of 1D wave-like chains with hydrogen bonds and π-π interactions. Compound 1 was further characterized by powder X-ray diffraction（PXRD）, infrared（IR） spectroscopy, thermogravimertic analysis（TG） and elemental analysis. Additionally, the magnetic property of compound 1 was also investigated.

关 键 词：Coordination polymer Supramolecular architecture SOLVOTHERMAL Magnetic property 

分 类 号：O641.3[理学—物理化学] TQ463.23[理学—化学]